Zirconium trisulfide as a promising cathode material for Li primary thermal batteries

Kyriakos Giagloglou; Julia Louise Payne; Christina Crouch; Richard Gover; Paul Alexander Connor; John Thomas Sirr Irvine

doi:10.1149/2.1351614jes

Zirconium trisulfide as a promising cathode material for Li primary thermal batteries

Kyriakos Giagloglou
, Julia Louise Payne
, Christina Crouch
, Richard Gover
, Paul Alexander Connor
, John Thomas Sirr Irvine

Research output: Contribution to journal › Article › peer-review

Abstract

In this work ZrS₃ has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS₃ before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr₂S₄, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li₁₃Si₄ by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °C a single voltage plateau of 1.70 V at a current density of 11 mA/cm² was achieved with capacity of 357 mA h g^-1. Therefore ZrS₃ material has some promise as a cathode for Li thermal batteries.

Original language	English
Journal	Journal of The Electrochemical Society
Volume	163
Issue number	14
DOIs	https://doi.org/10.1149/2.1351614jes
Publication status	Published - 25 Nov 2016

Keywords

Cathode
Discharge at high temperature
Li thermal battery
LiZr2S4
Solid state reaction
ZrS

Access to Document

10.1149/2.1351614jesLicence: CC BY

Irvine_2016_JTES_Zirconium_CCBY-VoR
© The Authors 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
Final published version, 931 KBLicence: CC BY

Handle.net

Persistent link

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application
Irvine, J. (PI), Cassidy, M. (CoI), Connor, P. (CoI), Savaniu, C. (CoI) & Zhou, W. (CoI)
EPSRC
7/01/13 → 6/01/18
Project: Standard
Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry
Irvine, J. (PI)
The Royal Society
1/08/12 → 31/07/17
Project: Standard

The identification and down selection of suitable cathode materials for use in next generation thermal batteries
Giagloglou, K. (Author), Irvine, J. T. S. (Supervisor) & Connor, P. A. (Supervisor), 7 Dec 2017
Student thesis: Doctoral Thesis (PhD)

Cite this

@article{f3a042ecaec24c5d9c3b58bd87a726e1,

title = "Zirconium trisulfide as a promising cathode material for Li primary thermal batteries",

abstract = "In this work ZrS3 has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS3 before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr2S4, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) {\AA} cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li13Si4 by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °C a single voltage plateau of 1.70 V at a current density of 11 mA/cm2 was achieved with capacity of 357 mA h g-1. Therefore ZrS3 material has some promise as a cathode for Li thermal batteries.",

keywords = "Cathode, Discharge at high temperature, Li thermal battery, LiZr2S4, Solid state reaction , ZrS",

author = "Kyriakos Giagloglou and Payne, \{Julia Louise\} and Christina Crouch and Richard Gover and Connor, \{Paul Alexander\} and Irvine, \{John Thomas Sirr\}",

year = "2016",

month = nov,

day = "25",

doi = "10.1149/2.1351614jes",

language = "English",

volume = "163",

journal = "Journal of The Electrochemical Society",

issn = "0013-4651",

publisher = "IOP Publishing Ltd.",

number = "14",

}

TY - JOUR

T1 - Zirconium trisulfide as a promising cathode material for Li primary thermal batteries

AU - Giagloglou, Kyriakos

AU - Payne, Julia Louise

AU - Crouch, Christina

AU - Gover, Richard

AU - Connor, Paul Alexander

AU - Irvine, John Thomas Sirr

PY - 2016/11/25

Y1 - 2016/11/25

N2 - In this work ZrS3 has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS3 before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr2S4, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li13Si4 by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °C a single voltage plateau of 1.70 V at a current density of 11 mA/cm2 was achieved with capacity of 357 mA h g-1. Therefore ZrS3 material has some promise as a cathode for Li thermal batteries.

AB - In this work ZrS3 has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS3 before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr2S4, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li13Si4 by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °C a single voltage plateau of 1.70 V at a current density of 11 mA/cm2 was achieved with capacity of 357 mA h g-1. Therefore ZrS3 material has some promise as a cathode for Li thermal batteries.

KW - Cathode

KW - Discharge at high temperature

KW - Li thermal battery

KW - LiZr2S4

KW - Solid state reaction

KW - ZrS

U2 - 10.1149/2.1351614jes

DO - 10.1149/2.1351614jes

M3 - Article

SN - 0013-4651

VL - 163

JO - Journal of The Electrochemical Society

JF - Journal of The Electrochemical Society

IS - 14

ER -

Zirconium trisulfide as a promising cathode material for Li primary thermal batteries

Abstract

Keywords

Access to Document

Handle.net

Fingerprint

Projects

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application

Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry

Student theses

The identification and down selection of suitable cathode materials for use in next generation thermal batteries

Cite this