Weak Te,Te interactions through the looking glass of NMR spin-spin coupling

Michael Buehl; Fergus Ross Knight; Anezka Kristkova; Irina Ondik; Olga Malkina; Rebecca Amy Michele Randall; Alexandra Martha Zoya Slawin; J Derek Woollins

doi:10.1002/anie.201205998

Weak Te,Te interactions through the looking glass of NMR spin-spin coupling

Michael Buehl, Fergus Ross Knight, Anezka Kristkova, Irina Ondik, Olga Malkina, Rebecca Amy Michele Randall, Alexandra Martha Zoya Slawin, J Derek Woollins

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Abstract

Across the bay: J(125Te,125Te) spin–spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems.

Original language	English
Pages (from-to)	2495-2498
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	52
Issue number	9
Early online date	23 Jan 2013
DOIs	https://doi.org/10.1002/anie.201205998
Publication status	Published - 2013

Keywords

Quantum-chemical computation
Chemical bond
Electron delocalisation
Peri-substituted naphthalene derivatives

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10.1002/anie.201205998

Buhletal2013AngChemInt52 9WeakTe
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is a Wiley OnlineOpen article.
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Cite this

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title = "Weak Te,Te interactions through the looking glass of NMR spin-spin coupling",

abstract = "Across the bay: J(125Te,125Te) spin–spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems.",

keywords = "Quantum-chemical computation, Chemical bond, Electron delocalisation, Peri-substituted naphthalene derivatives",

author = "Michael Buehl and Knight, {Fergus Ross} and Anezka Kristkova and Irina Ondik and Olga Malkina and Randall, {Rebecca Amy Michele} and Slawin, {Alexandra Martha Zoya} and Woollins, {J Derek}",

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AU - Buehl, Michael

AU - Knight, Fergus Ross

AU - Kristkova, Anezka

AU - Ondik, Irina

AU - Malkina, Olga

AU - Randall, Rebecca Amy Michele

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, J Derek

PY - 2013

Y1 - 2013

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AB - Across the bay: J(125Te,125Te) spin–spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems.

KW - Quantum-chemical computation

KW - Chemical bond

KW - Electron delocalisation

KW - Peri-substituted naphthalene derivatives

U2 - 10.1002/anie.201205998

DO - 10.1002/anie.201205998

M3 - Article

SN - 1433-7851

VL - 52

SP - 2495

EP - 2498

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 9

ER -

Weak Te,Te interactions through the looking glass of NMR spin-spin coupling

Abstract

Keywords

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