Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials

C S J  Cazin; M  Veith; P  Braunstein; R B  Bedford

Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials

C S J Cazin, M Veith, P Braunstein, R B Bedford

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Versatile methodologies for the synthesis of N-alkyl and N-aryl, and alkoxysilyl-functionalised mono- and bis-imidazolium salts are discussed. Such salts could find applications for heterogeneous N-heterocyclic catalysts and sol-gel materials.

Original language	English
Pages (from-to)	622-626
Number of pages	5
Journal	Synthesis
Issue number	4
Publication status	Published - 7 Mar 2005

Keywords

ionic liquids
carbenes
supported catalysis
imidazolium salts
alkoxysilyl
HETEROCYCLIC CARBENE COMPLEXES
SUPERCRITICAL CARBON-DIOXIDE
TEMPERATURE IONIC LIQUIDS
CROSS-COUPLING REACTIONS
OLEFIN-METATHESIS
SOLVENTS
PALLADIUM
ALKYLATION
REACTIVITY
RHODIUM

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@article{4abb047bd01d438ea2c1b37f247ef732,

title = "Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials",

abstract = "Versatile methodologies for the synthesis of N-alkyl and N-aryl, and alkoxysilyl-functionalised mono- and bis-imidazolium salts are discussed. Such salts could find applications for heterogeneous N-heterocyclic catalysts and sol-gel materials.",

keywords = "ionic liquids, carbenes, supported catalysis, imidazolium salts, alkoxysilyl, HETEROCYCLIC CARBENE COMPLEXES, SUPERCRITICAL CARBON-DIOXIDE, TEMPERATURE IONIC LIQUIDS, CROSS-COUPLING REACTIONS, OLEFIN-METATHESIS, SOLVENTS, PALLADIUM, ALKYLATION, REACTIVITY, RHODIUM",

author = "Cazin, {C S J} and M Veith and P Braunstein and Bedford, {R B}",

year = "2005",

month = mar,

day = "7",

language = "English",

pages = "622--626",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "4",

}

TY - JOUR

T1 - Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials

AU - Cazin, C S J

AU - Veith, M

AU - Braunstein, P

AU - Bedford, R B

PY - 2005/3/7

Y1 - 2005/3/7

N2 - Versatile methodologies for the synthesis of N-alkyl and N-aryl, and alkoxysilyl-functionalised mono- and bis-imidazolium salts are discussed. Such salts could find applications for heterogeneous N-heterocyclic catalysts and sol-gel materials.

AB - Versatile methodologies for the synthesis of N-alkyl and N-aryl, and alkoxysilyl-functionalised mono- and bis-imidazolium salts are discussed. Such salts could find applications for heterogeneous N-heterocyclic catalysts and sol-gel materials.

KW - ionic liquids

KW - carbenes

KW - supported catalysis

KW - imidazolium salts

KW - alkoxysilyl

KW - HETEROCYCLIC CARBENE COMPLEXES

KW - SUPERCRITICAL CARBON-DIOXIDE

KW - TEMPERATURE IONIC LIQUIDS

KW - CROSS-COUPLING REACTIONS

KW - OLEFIN-METATHESIS

KW - SOLVENTS

KW - PALLADIUM

KW - ALKYLATION

KW - REACTIVITY

KW - RHODIUM

M3 - Article

SN - 0039-7881

SP - 622

EP - 626

JO - Synthesis

JF - Synthesis

IS - 4

ER -

Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials

Abstract

Keywords

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