Variable dimensionality in 'hollow' hybrid tin iodide perovskites

Jason A. McNulty; Alexandra Martha Zoya Slawin; Philip Lightfoot

doi:10.1039/D0DT03449E

Variable dimensionality in 'hollow' hybrid tin iodide perovskites

Jason A. McNulty, Alexandra Martha Zoya Slawin, Philip Lightfoot^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Two ‘hollow’ B-site deficient perovskites, (TzH)₁₁(H₃PO₂)Sn₆I₂₃ and (TzH)₃Sn₂I₇ (TzH+ = 1,2,4-triazolium, H₃PO₂ = hypohosphorous acid), have been prepared. (TzH)₁₁(H₃PO₂)Sn₆I₂₃ is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)₃Sn₂I₇.

Original language	English
Journal	Dalton Transactions
Volume	Advance Articles
Early online date	26 Oct 2020
DOIs	https://doi.org/10.1039/D0DT03449E
Publication status	E-pub ahead of print - 26 Oct 2020

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Copyright © 2020 The Author(s). Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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Variable dimensionality in 'hollow' hybrid tin iodide perovskites (dataset)
McNulty, J. A. (Creator), Slawin, A. M. Z. (Creator) & Lightfoot, P. (Creator), University of St Andrews, 2020
DOI: 10.17630/30969c0d-61c9-4f69-822b-f953ae580ec7
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title = "Variable dimensionality in 'hollow' hybrid tin iodide perovskites",

abstract = "Two {\textquoteleft}hollow{\textquoteright} B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.",

author = "McNulty, {Jason A.} and Slawin, {Alexandra Martha Zoya} and Philip Lightfoot",

note = "We acknowledge support from the University of St Andrews and the Leverhulme trust (RPG-2018-065).",

year = "2020",

month = oct,

day = "26",

doi = "10.1039/D0DT03449E",

language = "English",

volume = "Advance Articles",

journal = "Dalton Transactions",

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TY - JOUR

T1 - Variable dimensionality in 'hollow' hybrid tin iodide perovskites

AU - McNulty, Jason A.

AU - Slawin, Alexandra Martha Zoya

AU - Lightfoot, Philip

N1 - We acknowledge support from the University of St Andrews and the Leverhulme trust (RPG-2018-065).

PY - 2020/10/26

Y1 - 2020/10/26

N2 - Two ‘hollow’ B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.

AB - Two ‘hollow’ B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.

U2 - 10.1039/D0DT03449E

DO - 10.1039/D0DT03449E

M3 - Article

SN - 1477-9226

VL - Advance Articles

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Variable dimensionality in 'hollow' hybrid tin iodide perovskites

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Variable dimensionality in 'hollow' hybrid tin iodide perovskites (dataset)

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