Variable dimensionality in 'hollow' hybrid tin iodide perovskites

Jason A. McNulty, Alexandra Martha Zoya Slawin, Philip Lightfoot*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Two ‘hollow’ B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.
Original languageEnglish
JournalDalton Transactions
VolumeAdvance Articles
Early online date26 Oct 2020
DOIs
Publication statusE-pub ahead of print - 26 Oct 2020

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