Vapour-phase-transport rearrangement technique for the synthesis of new zeolites

Valeryia Kasneryk; Mariya Shamzhy; Jingtian Zhou; Qiudi Yue; Michal Mazur; Alvaro Mayoral; Zhenlin Luo; Russell E. Morris; Jiří Čejka; Maksym Opanasenko

doi:10.1038/s41467-019-12882-3

Vapour-phase-transport rearrangement technique for the synthesis of new zeolites

Valeryia Kasneryk, Mariya Shamzhy, Jingtian Zhou, Qiudi Yue, Michal Mazur, Alvaro Mayoral, Zhenlin Luo, Russell E. Morris, Jiří Čejka, Maksym Opanasenko^*

^*Corresponding author for this work

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Abstract

Owing to the significant difference in the numbers of simulated and experimentally feasible zeolite structures, several alternative strategies have been developed for zeolite synthesis. Despite their rationality and originality, most of these techniques are based on trial-and-error, which makes it difficult to predict the structure of new materials. Assembly-Disassembly-Organization-Reassembly (ADOR) method overcoming this limitation was successfully applied to a limited number of structures with relatively stable crystalline layers (UTL, UOV, *CTH). Here, we report a straightforward, vapour-phase-transport strategy for the transformation of IWW zeolite with low-density silica layers connected by labile Ge-rich units into material with new topology. In situ XRD and XANES studies on the mechanism of IWW rearrangement reveal an unusual structural distortion-reconstruction of the framework throughout the process. Therefore, our findings provide a step forward towards engineering nanoporous materials and increasing the number of zeolites available for future applications.

Original language	English
Article number	5129
Number of pages	8
Journal	Nature Communications
Volume	10
DOIs	https://doi.org/10.1038/s41467-019-12882-3
Publication status	Published - 12 Nov 2019

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title = "Vapour-phase-transport rearrangement technique for the synthesis of new zeolites",

abstract = "Owing to the significant difference in the numbers of simulated and experimentally feasible zeolite structures, several alternative strategies have been developed for zeolite synthesis. Despite their rationality and originality, most of these techniques are based on trial-and-error, which makes it difficult to predict the structure of new materials. Assembly-Disassembly-Organization-Reassembly (ADOR) method overcoming this limitation was successfully applied to a limited number of structures with relatively stable crystalline layers (UTL, UOV, *CTH). Here, we report a straightforward, vapour-phase-transport strategy for the transformation of IWW zeolite with low-density silica layers connected by labile Ge-rich units into material with new topology. In situ XRD and XANES studies on the mechanism of IWW rearrangement reveal an unusual structural distortion-reconstruction of the framework throughout the process. Therefore, our findings provide a step forward towards engineering nanoporous materials and increasing the number of zeolites available for future applications.",

author = "Valeryia Kasneryk and Mariya Shamzhy and Jingtian Zhou and Qiudi Yue and Michal Mazur and Alvaro Mayoral and Zhenlin Luo and Morris, {Russell E.} and Ji{\v r}{\'i} {\v C}ejka and Maksym Opanasenko",

note = "M.S., M.M., R.E.M., J.{\v C}. and M.O. acknowledge OP VVV “Excellent Research Teams” project No.CZ.02.1.01/0.0/0.0/15_003/0000417– CUCAM. M.S. and M.O. thank the Primus Research Program of the Charles University (project number PRIMUS/17/SCI/22 “Soluble zeolites”). R.E.M. also thanks the ERC (Advanced Grant 787073 “ADOR”). A.M. acknowledges The Centre for High-resolution Electron Microscopy (CħEM), supported by SPST of ShanghaiTech University under contract No. EM02161943, and the Natural National Science Foundation of China, through projects NFSC-21850410448 and NSFC- 21835002. Z.L. acknowledges the support from the National Key Research and Development Program of China (2016YFA0300102) and the National Natural Science Foundation of China (11675179, 11434009). J.{\v C}. acknowledges the support of the Czech Science Foundation to the project EXPRO (19-27551×).",

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doi = "10.1038/s41467-019-12882-3",

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AU - Kasneryk, Valeryia

AU - Shamzhy, Mariya

AU - Zhou, Jingtian

AU - Yue, Qiudi

AU - Mazur, Michal

AU - Mayoral, Alvaro

AU - Luo, Zhenlin

AU - Morris, Russell E.

AU - Čejka, Jiří

AU - Opanasenko, Maksym

N1 - M.S., M.M., R.E.M., J.Č. and M.O. acknowledge OP VVV “Excellent Research Teams” project No.CZ.02.1.01/0.0/0.0/15_003/0000417– CUCAM. M.S. and M.O. thank the Primus Research Program of the Charles University (project number PRIMUS/17/SCI/22 “Soluble zeolites”). R.E.M. also thanks the ERC (Advanced Grant 787073 “ADOR”). A.M. acknowledges The Centre for High-resolution Electron Microscopy (CħEM), supported by SPST of ShanghaiTech University under contract No. EM02161943, and the Natural National Science Foundation of China, through projects NFSC-21850410448 and NSFC- 21835002. Z.L. acknowledges the support from the National Key Research and Development Program of China (2016YFA0300102) and the National Natural Science Foundation of China (11675179, 11434009). J.Č. acknowledges the support of the Czech Science Foundation to the project EXPRO (19-27551×).

PY - 2019/11/12

Y1 - 2019/11/12

N2 - Owing to the significant difference in the numbers of simulated and experimentally feasible zeolite structures, several alternative strategies have been developed for zeolite synthesis. Despite their rationality and originality, most of these techniques are based on trial-and-error, which makes it difficult to predict the structure of new materials. Assembly-Disassembly-Organization-Reassembly (ADOR) method overcoming this limitation was successfully applied to a limited number of structures with relatively stable crystalline layers (UTL, UOV, *CTH). Here, we report a straightforward, vapour-phase-transport strategy for the transformation of IWW zeolite with low-density silica layers connected by labile Ge-rich units into material with new topology. In situ XRD and XANES studies on the mechanism of IWW rearrangement reveal an unusual structural distortion-reconstruction of the framework throughout the process. Therefore, our findings provide a step forward towards engineering nanoporous materials and increasing the number of zeolites available for future applications.

AB - Owing to the significant difference in the numbers of simulated and experimentally feasible zeolite structures, several alternative strategies have been developed for zeolite synthesis. Despite their rationality and originality, most of these techniques are based on trial-and-error, which makes it difficult to predict the structure of new materials. Assembly-Disassembly-Organization-Reassembly (ADOR) method overcoming this limitation was successfully applied to a limited number of structures with relatively stable crystalline layers (UTL, UOV, *CTH). Here, we report a straightforward, vapour-phase-transport strategy for the transformation of IWW zeolite with low-density silica layers connected by labile Ge-rich units into material with new topology. In situ XRD and XANES studies on the mechanism of IWW rearrangement reveal an unusual structural distortion-reconstruction of the framework throughout the process. Therefore, our findings provide a step forward towards engineering nanoporous materials and increasing the number of zeolites available for future applications.

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DO - 10.1038/s41467-019-12882-3

M3 - Article

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AN - SCOPUS:85074955372

SN - 2041-1723

VL - 10

JO - Nature Communications

JF - Nature Communications

M1 - 5129

ER -

Vapour-phase-transport rearrangement technique for the synthesis of new zeolites

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