Unusual potassium coordination in the 18-crown-6 tetraphenyldiselenoimidodiphosphinate complex and its sulfur analogue

K H  Ebert; R  CeaOlivares; V  GarciaMontalvo; G  EspinosaPerez; M R  Estrada; J  Novosad; J D  Woollins

Unusual potassium coordination in the 18-crown-6 tetraphenyldiselenoimidodiphosphinate complex and its sulfur analogue

K H Ebert, R CeaOlivares, V GarciaMontalvo, G EspinosaPerez, M R Estrada, J Novosad, J D Woollins

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A [K(18-crown-6)] salt of the (Ph(2)PSe)(2)NH ligand was obtained by reaction of [K(Ph(2)PSe)(2)N] with 18-crown-6 [monoclinic space group C2/c with the cell parameters a = 20.310(2), b = 8.894(2), c = 22.978(3) Angstrom, beta = 114.66(2)degrees, and Z = 4]. The potassium ion has the rare coordination number 10, It is coordinated to the six oxygen atoms of the crown ether and to four carbon atoms, two from each of the two anionic Ligands neighboring the cationic moiety.

Original language	English
Pages (from-to)	1145-1149
Number of pages	5
Journal	Zeitschrift für Naturforschung B - A Journal of Chemical Sciences
Volume	51
Issue number	8
Publication status	Published - Aug 1996

Keywords

potassium(18-crown-6) complex
tetraphenyldiselenoimidodiphosphinate
tetraphenyldithioimidophosphinate
phosphazene
ALKALINE-EARTH CATIONS
FREE CHELATE RINGS
X-RAY STRUCTURE
MOLECULAR-STRUCTURES
CRYSTAL-STRUCTURES
DERIVATIVES
CHEMISTRY
ARYL

Cite this

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title = "Unusual potassium coordination in the 18-crown-6 tetraphenyldiselenoimidodiphosphinate complex and its sulfur analogue",

abstract = "A [K(18-crown-6)] salt of the (Ph(2)PSe)(2)NH ligand was obtained by reaction of [K(Ph(2)PSe)(2)N] with 18-crown-6 [monoclinic space group C2/c with the cell parameters a = 20.310(2), b = 8.894(2), c = 22.978(3) Angstrom, beta = 114.66(2)degrees, and Z = 4]. The potassium ion has the rare coordination number 10, It is coordinated to the six oxygen atoms of the crown ether and to four carbon atoms, two from each of the two anionic Ligands neighboring the cationic moiety.",

keywords = "potassium(18-crown-6) complex, tetraphenyldiselenoimidodiphosphinate, tetraphenyldithioimidophosphinate, phosphazene, ALKALINE-EARTH CATIONS, FREE CHELATE RINGS, X-RAY STRUCTURE, MOLECULAR-STRUCTURES, CRYSTAL-STRUCTURES, DERIVATIVES, CHEMISTRY, ARYL",

author = "Ebert, {K H} and R CeaOlivares and V GarciaMontalvo and G EspinosaPerez and Estrada, {M R} and J Novosad and Woollins, {J D}",

year = "1996",

month = aug,

language = "English",

volume = "51",

pages = "1145--1149",

journal = "Zeitschrift f{\"u}r Naturforschung B - A Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "de Gruyter",

number = "8",

}

TY - JOUR

T1 - Unusual potassium coordination in the 18-crown-6 tetraphenyldiselenoimidodiphosphinate complex and its sulfur analogue

AU - Ebert, K H

AU - CeaOlivares, R

AU - GarciaMontalvo, V

AU - EspinosaPerez, G

AU - Estrada, M R

AU - Novosad, J

AU - Woollins, J D

PY - 1996/8

Y1 - 1996/8

N2 - A [K(18-crown-6)] salt of the (Ph(2)PSe)(2)NH ligand was obtained by reaction of [K(Ph(2)PSe)(2)N] with 18-crown-6 [monoclinic space group C2/c with the cell parameters a = 20.310(2), b = 8.894(2), c = 22.978(3) Angstrom, beta = 114.66(2)degrees, and Z = 4]. The potassium ion has the rare coordination number 10, It is coordinated to the six oxygen atoms of the crown ether and to four carbon atoms, two from each of the two anionic Ligands neighboring the cationic moiety.

AB - A [K(18-crown-6)] salt of the (Ph(2)PSe)(2)NH ligand was obtained by reaction of [K(Ph(2)PSe)(2)N] with 18-crown-6 [monoclinic space group C2/c with the cell parameters a = 20.310(2), b = 8.894(2), c = 22.978(3) Angstrom, beta = 114.66(2)degrees, and Z = 4]. The potassium ion has the rare coordination number 10, It is coordinated to the six oxygen atoms of the crown ether and to four carbon atoms, two from each of the two anionic Ligands neighboring the cationic moiety.

KW - potassium(18-crown-6) complex

KW - tetraphenyldiselenoimidodiphosphinate

KW - tetraphenyldithioimidophosphinate

KW - phosphazene

KW - ALKALINE-EARTH CATIONS

KW - FREE CHELATE RINGS

KW - X-RAY STRUCTURE

KW - MOLECULAR-STRUCTURES

KW - CRYSTAL-STRUCTURES

KW - DERIVATIVES

KW - CHEMISTRY

KW - ARYL

M3 - Article

SN - 0932-0776

VL - 51

SP - 1145

EP - 1149

JO - Zeitschrift für Naturforschung B - A Journal of Chemical Sciences

JF - Zeitschrift für Naturforschung B - A Journal of Chemical Sciences

IS - 8

ER -

Unusual potassium coordination in the 18-crown-6 tetraphenyldiselenoimidodiphosphinate complex and its sulfur analogue

Abstract

Keywords

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