Unusual Pathway of the Reaction of 4-Benzoyl-5-phenylfuran-2,3-dione with Acetylmethylenetriphenylphosphorane and Methyl Triphenylphosphoranylideneacetate

E N Koz'minykh; V I Goncharov; Robert Alan Aitken; V O Koz'minykh

doi:10.1134/S1070363206080081

Unusual Pathway of the Reaction of 4-Benzoyl-5-phenylfuran-2,3-dione with Acetylmethylenetriphenylphosphorane and Methyl Triphenylphosphoranylideneacetate

E N Koz'minykh, V I Goncharov, Robert Alan Aitken, V O Koz'minykh

Research output: Contribution to journal › Article › peer-review

Abstract

4-Benzoyl-5-phenylfuran-2,3-dione reacts with acetylmethylenetriphenylphosphorane or methyl triphenylphosphoranylideneacetate to form 1:1 adducts of 4-benzoyl-2-hydroxy-2-(2-oxopropyl)-5-phenylfuran-3(2H)-one or methyl 4-benzoyl-2-hydroxy-3-oxo-5-phenyl-2,3-dihydrofuran-2-ylacetate, respectively, with triphenylphosphine oxide. Structural features of the products are discussed.

Original language	English
Pages (from-to)	1226-1231
Number of pages	6
Journal	Russian Journal of General Chemistry
Volume	76
Issue number	8
DOIs	https://doi.org/10.1134/S1070363206080081
Publication status	Published - Aug 2006

Keywords

BIOLOGICAL-ACTIVITY
WITTIG REACTION
CHEMISTRY
ESTERS
OXALYMETHYLENEPHOSPHORANES
DERIVATIVES

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title = "Unusual Pathway of the Reaction of 4-Benzoyl-5-phenylfuran-2,3-dione with Acetylmethylenetriphenylphosphorane and Methyl Triphenylphosphoranylideneacetate",

abstract = "4-Benzoyl-5-phenylfuran-2,3-dione reacts with acetylmethylenetriphenylphosphorane or methyl triphenylphosphoranylideneacetate to form 1:1 adducts of 4-benzoyl-2-hydroxy-2-(2-oxopropyl)-5-phenylfuran-3(2H)-one or methyl 4-benzoyl-2-hydroxy-3-oxo-5-phenyl-2,3-dihydrofuran-2-ylacetate, respectively, with triphenylphosphine oxide. Structural features of the products are discussed.",

keywords = "BIOLOGICAL-ACTIVITY, WITTIG REACTION, CHEMISTRY, ESTERS, OXALYMETHYLENEPHOSPHORANES, DERIVATIVES",

author = "Koz'minykh, {E N} and Goncharov, {V I} and Aitken, {Robert Alan} and Koz'minykh, {V O}",

year = "2006",

month = aug,

doi = "10.1134/S1070363206080081",

language = "English",

volume = "76",

pages = "1226--1231",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "8",

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T1 - Unusual Pathway of the Reaction of 4-Benzoyl-5-phenylfuran-2,3-dione with Acetylmethylenetriphenylphosphorane and Methyl Triphenylphosphoranylideneacetate

AU - Koz'minykh, E N

AU - Goncharov, V I

AU - Aitken, Robert Alan

AU - Koz'minykh, V O

PY - 2006/8

Y1 - 2006/8

N2 - 4-Benzoyl-5-phenylfuran-2,3-dione reacts with acetylmethylenetriphenylphosphorane or methyl triphenylphosphoranylideneacetate to form 1:1 adducts of 4-benzoyl-2-hydroxy-2-(2-oxopropyl)-5-phenylfuran-3(2H)-one or methyl 4-benzoyl-2-hydroxy-3-oxo-5-phenyl-2,3-dihydrofuran-2-ylacetate, respectively, with triphenylphosphine oxide. Structural features of the products are discussed.

AB - 4-Benzoyl-5-phenylfuran-2,3-dione reacts with acetylmethylenetriphenylphosphorane or methyl triphenylphosphoranylideneacetate to form 1:1 adducts of 4-benzoyl-2-hydroxy-2-(2-oxopropyl)-5-phenylfuran-3(2H)-one or methyl 4-benzoyl-2-hydroxy-3-oxo-5-phenyl-2,3-dihydrofuran-2-ylacetate, respectively, with triphenylphosphine oxide. Structural features of the products are discussed.

KW - BIOLOGICAL-ACTIVITY

KW - WITTIG REACTION

KW - CHEMISTRY

KW - ESTERS

KW - OXALYMETHYLENEPHOSPHORANES

KW - DERIVATIVES

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DO - 10.1134/S1070363206080081

M3 - Article

SN - 1070-3632

VL - 76

SP - 1226

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JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

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ER -

Unusual Pathway of the Reaction of 4-Benzoyl-5-phenylfuran-2,3-dione with Acetylmethylenetriphenylphosphorane and Methyl Triphenylphosphoranylideneacetate

Abstract

Keywords

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