Projects per year
Abstract
Solid-state NMR spectra of new P–Se heterocycles based on peri-substituted naphthalene motifs show the presence of unusual J couplings between Se and P. These couplings are between atoms in adjacent molecules and occur “through space”, rather than through conventional covalent bonds. Experimental measurements are supported by relativistic DFT calculations, which confirm the presence of couplings between nonbonded atoms, and provide information on the pathway of the interaction. This observation improves the understanding of J couplings and offers insight into the factors that affect crystal packing in solids, for future synthetic exploitation.
Original language | English |
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Pages (from-to) | 6172-6175 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 137 |
Issue number | 19 |
Early online date | 30 Apr 2015 |
DOIs | |
Publication status | Published - 20 May 2015 |
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Dive into the research topics of 'Unusual intermolecular “through-space” J couplings in P–Se heterocycles'. Together they form a unique fingerprint.Projects
- 7 Finished
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Impact Acceleration Account: Impact Acceleration Account
Woollins, J. D. (PI)
1/10/15 → 31/03/17
Project: Standard
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Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation
Woollins, J. D. (PI), Ashbrook, S. E. (CoI), Morris, R. E. (CoI) & Slawin, A. M. Z. (CoI)
1/01/13 → 31/03/13
Project: Standard
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Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research
Woollins, J. D. (PI)
1/11/12 → 31/03/13
Project: Standard
Profiles
Datasets
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Data underpinning Unusual Intermolecular “Through-Space” J Couplings in P–Se Heterocycles
Ashbrook, S. E. M. (Creator), University of St Andrews, 2015
DOI: 10.17630/6971BCF1-4FBA-4FA1-AEF2-C213A740D36F
Dataset
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