Unprecedented steric deformation of ortho-carborane

Brian W. Hutton; Fraser MacIntosh; David Ellis; Fabien Herisse; Stuart A. Macgregor; David Mckay; Victoria Petrie-Armstrong; Georgina M. Rosair; Dmitry S. Perekalin; Hugo Tricas; Alan J. Welch

doi:10.1039/b810702e

Unprecedented steric deformation of ortho-carborane

Brian W. Hutton, Fraser MacIntosh, David Ellis, Fabien Herisse, Stuart A. Macgregor^*, David Mckay, Victoria Petrie-Armstrong, Georgina M. Rosair, Dmitry S. Perekalin, Hugo Tricas, Alan J. Welch

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities..

Original language	English
Pages (from-to)	5345-5347
Number of pages	3
Journal	Chemical Communications
Issue number	42
DOIs	https://doi.org/10.1039/b810702e
Publication status	Published - 2008

Keywords

EQUALS P-CYMENE
MOLECULAR-STRUCTURES
ISOMERIZED PRODUCTS
STRUCTURAL-CHARACTERIZATION
LOW-TEMPERATURE
EXO-NIDO
CRYSTAL
ANIONS
CARBABORANES
B10C2H12

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@article{87bc70203ffb4c2180c2dc80789f04d2,

title = "Unprecedented steric deformation of ortho-carborane",

abstract = "The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities..",

keywords = "EQUALS P-CYMENE, MOLECULAR-STRUCTURES, ISOMERIZED PRODUCTS, STRUCTURAL-CHARACTERIZATION, LOW-TEMPERATURE, EXO-NIDO, CRYSTAL, ANIONS, CARBABORANES, B10C2H12",

author = "Hutton, {Brian W.} and Fraser MacIntosh and David Ellis and Fabien Herisse and Macgregor, {Stuart A.} and David Mckay and Victoria Petrie-Armstrong and Rosair, {Georgina M.} and Perekalin, {Dmitry S.} and Hugo Tricas and Welch, {Alan J.}",

year = "2008",

doi = "10.1039/b810702e",

language = "English",

pages = "5345--5347",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "42",

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TY - JOUR

T1 - Unprecedented steric deformation of ortho-carborane

AU - Hutton, Brian W.

AU - MacIntosh, Fraser

AU - Ellis, David

AU - Herisse, Fabien

AU - Macgregor, Stuart A.

AU - Mckay, David

AU - Petrie-Armstrong, Victoria

AU - Rosair, Georgina M.

AU - Perekalin, Dmitry S.

AU - Tricas, Hugo

AU - Welch, Alan J.

PY - 2008

Y1 - 2008

N2 - The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities..

AB - The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities..

KW - EQUALS P-CYMENE

KW - MOLECULAR-STRUCTURES

KW - ISOMERIZED PRODUCTS

KW - STRUCTURAL-CHARACTERIZATION

KW - LOW-TEMPERATURE

KW - EXO-NIDO

KW - CRYSTAL

KW - ANIONS

KW - CARBABORANES

KW - B10C2H12

U2 - 10.1039/b810702e

DO - 10.1039/b810702e

M3 - Article

SN - 1359-7345

SP - 5345

EP - 5347

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Unprecedented steric deformation of ortho-carborane

Abstract

Keywords

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