Unprecedented steric deformation of ortho-carborane

Brian W. Hutton, Fraser MacIntosh, David Ellis, Fabien Herisse, Stuart A. Macgregor*, David Mckay, Victoria Petrie-Armstrong, Georgina M. Rosair, Dmitry S. Perekalin, Hugo Tricas, Alan J. Welch

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities..

Original languageEnglish
Pages (from-to)5345-5347
Number of pages3
JournalChemical Communications
Issue number42
DOIs
Publication statusPublished - 2008

Keywords

  • EQUALS P-CYMENE
  • MOLECULAR-STRUCTURES
  • ISOMERIZED PRODUCTS
  • STRUCTURAL-CHARACTERIZATION
  • LOW-TEMPERATURE
  • EXO-NIDO
  • CRYSTAL
  • ANIONS
  • CARBABORANES
  • B10C2H12

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