Unique carbon-carbon bond homolysis in 3-alkylcyclohexa-1,4-dienyl-3-carboxylic acid radicals

Paul A. Baguley; Gavin Binmore; Aynsley Milne; John C. Walton

doi:10.1039/CC9960002199

Unique carbon-carbon bond homolysis in 3-alkylcyclohexa-1,4-dienyl-3-carboxylic acid radicals

Paul A. Baguley, Gavin Binmore, Aynsley Milne, John C. Walton^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

3-Substituted cyclohexadienyl radicals generated by hydrogen abstraction from 3-alkylcyclohexa-1,4-diene-3-carboxylic acids readily fragment to produce alkyl radicals and benzoic acid; suitably functionalised alkyl groups cyclize in moderate yields.

Original language	English
Pages (from-to)	2199-2200
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/CC9960002199
Publication status	Published - 1 Jan 1996

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title = "Unique carbon-carbon bond homolysis in 3-alkylcyclohexa-1,4-dienyl-3-carboxylic acid radicals",

abstract = "3-Substituted cyclohexadienyl radicals generated by hydrogen abstraction from 3-alkylcyclohexa-1,4-diene-3-carboxylic acids readily fragment to produce alkyl radicals and benzoic acid; suitably functionalised alkyl groups cyclize in moderate yields.",

author = "Baguley, {Paul A.} and Gavin Binmore and Aynsley Milne and Walton, {John C.}",

year = "1996",

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AU - Baguley, Paul A.

AU - Binmore, Gavin

AU - Milne, Aynsley

AU - Walton, John C.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - 3-Substituted cyclohexadienyl radicals generated by hydrogen abstraction from 3-alkylcyclohexa-1,4-diene-3-carboxylic acids readily fragment to produce alkyl radicals and benzoic acid; suitably functionalised alkyl groups cyclize in moderate yields.

AB - 3-Substituted cyclohexadienyl radicals generated by hydrogen abstraction from 3-alkylcyclohexa-1,4-diene-3-carboxylic acids readily fragment to produce alkyl radicals and benzoic acid; suitably functionalised alkyl groups cyclize in moderate yields.

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EP - 2200

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Unique carbon-carbon bond homolysis in 3-alkylcyclohexa-1,4-dienyl-3-carboxylic acid radicals

Abstract

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