Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

R Alan Aitken; Adebayo O Oyewale

doi:10.1039/C4RA15004J

Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

Research output: Contribution to journal › Article › peer-review

Abstract

A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.

Original language	English
Pages (from-to)	19379-19381
Number of pages	3
Journal	RSC Advances
Volume	5
Issue number	25
Early online date	9 Feb 2015
DOIs	https://doi.org/10.1039/C4RA15004J
Publication status	Published - 17 Feb 2015

Access to Document

10.1039/C4RA15004J

aitken2014rscadvances19379
© 2015. The Royal Society of Chemistry. Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Final published version, 210 KB

Cite this

@article{017e6bacb5b645789291765308fd6b86,

title = "Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes",

abstract = "A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.",

author = "Aitken, \{R Alan\} and Oyewale, \{Adebayo O\}",

year = "2015",

month = feb,

day = "17",

doi = "10.1039/C4RA15004J",

language = "English",

volume = "5",

pages = "19379--19381",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "25",

}

TY - JOUR

T1 - Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

AU - Aitken, R Alan

AU - Oyewale, Adebayo O

PY - 2015/2/17

Y1 - 2015/2/17

N2 - A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.

AB - A range of halogenated methylthiophenes undergo dehalogenative condensation upon FVP over magnesium or calcium to give products including benzodithiophenes; in some cases this involves a novel rearrangement by equilibration of alkenylthienyl radicals via thiophene-fused cyclopropylmethyl intermediates.

UR - https://www.scopus.com/pages/publications/84923323495

U2 - 10.1039/C4RA15004J

DO - 10.1039/C4RA15004J

M3 - Article

SN - 2046-2069

VL - 5

SP - 19379

EP - 19381

JO - RSC Advances

JF - RSC Advances

IS - 25

ER -

Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this