Understanding the synthesis and reactivity of ADORable zeolites using NMR spectroscopy

Sharon E. Ashbrook; Russell E. Morris; Cameron Mark Rice

doi:10.1016/j.cocis.2022.101634

Understanding the synthesis and reactivity of ADORable zeolites using NMR spectroscopy

Sharon E. Ashbrook^*, Russell E. Morris^*, Cameron Mark Rice

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Zeolites remain one of the most important class of industrial catalyst used today, and with the urgent drive for transition from petrochemical to renewable feedstocks there is a renewed interest in developing new types of zeolite. Recent synthetic advances in the field have included the development of the Assembly-Disassembly-Organisation-Reassembly (ADOR) method. In this short review we will discuss how solid-state NMR experiments can be used to probe the mechanism of the process by characterising the structure of the intermediates and products, show how 17O NMR spectroscopy can be used to probe the reactivity of ADORable zeolites and explain how this in turn can lead to fundamental questions of how zeolites behave in the presence of liquid water.

Original language	English
Article number	101634
Number of pages	14
Journal	Current Opinion in Colloid & Interface Science
Volume	61
DOIs	https://doi.org/10.1016/j.cocis.2022.101634
Publication status	Published - 13 Oct 2022

Keywords

Solid-state NMR spectroscopy
Zeolites
ADOR
17O NMR

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.cocis.2022.101634Licence: CC BY

Ashbrook_2022_COCIS_ADORable_CC
Copyright © 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons. org/licenses/by/4.0/).
Final published version, 2.01 MBLicence: CC BY

H2020 ERC Advanced Grant 2017 ADOR: H2020 ERC Advanced Grant 2017 ADOR
Morris, R. E. (PI)
European Research Council
1/10/18 → 30/09/23
Project: Fellowship
EXONMR: EU FP7 Consolidator 2013 EXONMR
Ashbrook, S. E. (PI)
European Research Council
1/04/14 → 30/09/19
Project: Standard

Understanding the Synthesis and Reactivity of ADORable Zeolites using NMR Spectroscopy (dataset)
Ashbrook, S. E. (Creator), Morris, R. E. (Creator) & Rice, C. M. (Creator), University of St Andrews, 30 Sept 2022
DOI: 10.17630/d82e58e4-b4a0-40b3-8156-5cbf80eeea72
Dataset

File

Cite this

@article{1dfd4a800e6744179df553d2a40f7557,

title = "Understanding the synthesis and reactivity of ADORable zeolites using NMR spectroscopy",

abstract = "Zeolites remain one of the most important class of industrial catalyst used today, and with the urgent drive for transition from petrochemical to renewable feedstocks there is a renewed interest in developing new types of zeolite. Recent synthetic advances in the field have included the development of the Assembly-Disassembly-Organisation-Reassembly (ADOR) method. In this short review we will discuss how solid-state NMR experiments can be used to probe the mechanism of the process by characterising the structure of the intermediates and products, show how 17O NMR spectroscopy can be used to probe the reactivity of ADORable zeolites and explain how this in turn can lead to fundamental questions of how zeolites behave in the presence of liquid water.",

keywords = "Solid-state NMR spectroscopy, Zeolites, ADOR, 17O NMR",

author = "Ashbrook, {Sharon E.} and Morris, {Russell E.} and Rice, {Cameron Mark}",

note = "Funding: The authors would like to thank the ERC (EU FP7 Consolidator Grant 614290 EXONMR and Advanced Grant 787073 ADOR) and EPSRC (EP/N509759/1) for a studentship for CMR. The research data (and/or materials) supporting this publication can be accessed at https://doi.org/10.17630/d82e58e4-b4a0-40b3-8156-5cbf80eeea72",

year = "2022",

month = oct,

day = "13",

doi = "10.1016/j.cocis.2022.101634",

language = "English",

volume = "61",

journal = "Current Opinion in Colloid & Interface Science",

issn = "1359-0294",

publisher = "Elsevier",

}

TY - JOUR

T1 - Understanding the synthesis and reactivity of ADORable zeolites using NMR spectroscopy

AU - Ashbrook, Sharon E.

AU - Morris, Russell E.

AU - Rice, Cameron Mark

N1 - Funding: The authors would like to thank the ERC (EU FP7 Consolidator Grant 614290 EXONMR and Advanced Grant 787073 ADOR) and EPSRC (EP/N509759/1) for a studentship for CMR. The research data (and/or materials) supporting this publication can be accessed at https://doi.org/10.17630/d82e58e4-b4a0-40b3-8156-5cbf80eeea72

PY - 2022/10/13

Y1 - 2022/10/13

N2 - Zeolites remain one of the most important class of industrial catalyst used today, and with the urgent drive for transition from petrochemical to renewable feedstocks there is a renewed interest in developing new types of zeolite. Recent synthetic advances in the field have included the development of the Assembly-Disassembly-Organisation-Reassembly (ADOR) method. In this short review we will discuss how solid-state NMR experiments can be used to probe the mechanism of the process by characterising the structure of the intermediates and products, show how 17O NMR spectroscopy can be used to probe the reactivity of ADORable zeolites and explain how this in turn can lead to fundamental questions of how zeolites behave in the presence of liquid water.

AB - Zeolites remain one of the most important class of industrial catalyst used today, and with the urgent drive for transition from petrochemical to renewable feedstocks there is a renewed interest in developing new types of zeolite. Recent synthetic advances in the field have included the development of the Assembly-Disassembly-Organisation-Reassembly (ADOR) method. In this short review we will discuss how solid-state NMR experiments can be used to probe the mechanism of the process by characterising the structure of the intermediates and products, show how 17O NMR spectroscopy can be used to probe the reactivity of ADORable zeolites and explain how this in turn can lead to fundamental questions of how zeolites behave in the presence of liquid water.

KW - Solid-state NMR spectroscopy

KW - Zeolites

KW - ADOR

KW - 17O NMR

U2 - 10.1016/j.cocis.2022.101634

DO - 10.1016/j.cocis.2022.101634

M3 - Article

SN - 1359-0294

VL - 61

JO - Current Opinion in Colloid & Interface Science

JF - Current Opinion in Colloid & Interface Science

M1 - 101634

ER -

Understanding the synthesis and reactivity of ADORable zeolites using NMR spectroscopy

Abstract

Keywords

UN SDGs

Access to Document

Fingerprint

Projects

H2020 ERC Advanced Grant 2017 ADOR: H2020 ERC Advanced Grant 2017 ADOR

EXONMR: EU FP7 Consolidator 2013 EXONMR

Datasets

Understanding the Synthesis and Reactivity of ADORable Zeolites using NMR Spectroscopy (dataset)

Cite this