Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O V Magdysyuk; F Adams; H-P Liermann; I Spanopoulos; P N Trikalitis; M Hirscher; R E Morris; M J Duncan; L J McCormick; R E Dinnebier

doi:10.1039/c4cp03298e

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O V Magdysyuk, F Adams, H-P Liermann, I Spanopoulos, P N Trikalitis, M Hirscher, R E Morris, M J Duncan, L J McCormick, R E Dinnebier

Research output: Contribution to journal › Article › peer-review

Abstract

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

Original language	English
Pages (from-to)	23908-23914
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	16
Issue number	43
Early online date	17 Sept 2014
DOIs	https://doi.org/10.1039/c4cp03298e
Publication status	Published - 21 Nov 2014

Access to Document

10.1039/c4cp03298e

Magdysyuk_CPO-27_ZIF-8
© the Authors 2014. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4CP03298E
Accepted author manuscript, 691 KB

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks
Morris, R. E. (PI)
EPSRC
1/03/13 → 28/02/16
Project: Standard

Cite this

@article{e55708f1413c4c1eb1bd6fcf3880f2b4,

title = "Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8",

abstract = "An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.",

author = "Magdysyuk, {O V} and F Adams and H-P Liermann and I Spanopoulos and Trikalitis, {P N} and M Hirscher and Morris, {R E} and Duncan, {M J} and McCormick, {L J} and Dinnebier, {R E}",

year = "2014",

month = nov,

day = "21",

doi = "10.1039/c4cp03298e",

language = "English",

volume = "16",

pages = "23908--23914",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "ROYAL SOC CHEMISTRY",

number = "43",

}

TY - JOUR

T1 - Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

AU - Magdysyuk, O V

AU - Adams, F

AU - Liermann, H-P

AU - Spanopoulos, I

AU - Trikalitis, P N

AU - Hirscher, M

AU - Morris, R E

AU - Duncan, M J

AU - McCormick, L J

AU - Dinnebier, R E

PY - 2014/11/21

Y1 - 2014/11/21

N2 - An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

AB - An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

U2 - 10.1039/c4cp03298e

DO - 10.1039/c4cp03298e

M3 - Article

C2 - 25277596

SN - 1463-9076

VL - 16

SP - 23908

EP - 23914

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 43

ER -

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

Abstract

Access to Document

Fingerprint

Projects

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks

Cite this