Two novel self-interpenetrating 3D iron(II) coordination frameworks: synthesis, spectroscopic and structural characterizations with magnetic properties

Zouaoui Setifi; Abderazzak Addala; Jun Tao; Nanthawat Wannarit; Christopher Glidewell; Fatima Setifi; Sujittra Youngme

doi:10.1016/j.inoche.2016.04.005

Two novel self-interpenetrating 3D iron(II) coordination frameworks: synthesis, spectroscopic and structural characterizations with magnetic properties

Zouaoui Setifi, Abderazzak Addala, Jun Tao, Nanthawat Wannarit, Christopher Glidewell, Fatima Setifi, Sujittra Youngme

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag₂(CN)₃]₂}_n (I) and {Fe(4,4′-bpy)[Ag(CN)₂]₂[AgCN]₂}_n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag₂(CN)₃]⁻ species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)₂]⁻ resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by Ag^I ⋯ Ag^I interactions. Their magnetic properties exhibit high spin behavior.

Original language	English
Pages (from-to)	80-84
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	68
Early online date	16 Apr 2016
DOIs	https://doi.org/10.1016/j.inoche.2016.04.005
Publication status	Published - 1 Jun 2016

Keywords

Fe(II) coordination frameworks
Self-interpenetrate
AgI ⋯ AgI
Magnetic properties

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© 2016 Elsevier B.V. All rights reserved. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1016/j.inoche.2016.04.005
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@article{3fe3d4d45a5c4340b8c03a30bcc3760e,

title = "Two novel self-interpenetrating 3D iron(II) coordination frameworks: synthesis, spectroscopic and structural characterizations with magnetic properties",

abstract = "Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely \{Fe(4,4′-bpy)[Ag2(CN)3]2\}n (I) and \{Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2\}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]− species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]− resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.",

keywords = "Fe(II) coordination frameworks, Self-interpenetrate, AgI ⋯ AgI, Magnetic properties",

author = "Zouaoui Setifi and Abderazzak Addala and Jun Tao and Nanthawat Wannarit and Christopher Glidewell and Fatima Setifi and Sujittra Youngme",

note = "The authors acknowledge the algerian MESRS (Minist{\`e}re de l'Enseignement Sup{\'e}rieur et de la Recherche Scientifique), the algerian DG-RSDT (Direction G{\'e}n{\'e}rale de la Recherche Scientifique et du D{\'e}veloppement Technologique) and Ferhat Abbas University for financial support. SY acknowledges The Thailand Research Fund (Grant No. BRG5680009), the National Research University Project of Thailand, Office of the Higher Education Commission, and the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education, Thailand. NW thanks Central Scientific Instrument Center (CSIC), Faculty of Science and Technology, Thammasat University, Thailand.",

year = "2016",

month = jun,

day = "1",

doi = "10.1016/j.inoche.2016.04.005",

language = "English",

volume = "68",

pages = "80--84",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

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TY - JOUR

T1 - Two novel self-interpenetrating 3D iron(II) coordination frameworks

T2 - synthesis, spectroscopic and structural characterizations with magnetic properties

AU - Setifi, Zouaoui

AU - Addala, Abderazzak

AU - Tao, Jun

AU - Wannarit, Nanthawat

AU - Glidewell, Christopher

AU - Setifi, Fatima

AU - Youngme, Sujittra

N1 - The authors acknowledge the algerian MESRS (Ministère de l'Enseignement Supérieur et de la Recherche Scientifique), the algerian DG-RSDT (Direction Générale de la Recherche Scientifique et du Développement Technologique) and Ferhat Abbas University for financial support. SY acknowledges The Thailand Research Fund (Grant No. BRG5680009), the National Research University Project of Thailand, Office of the Higher Education Commission, and the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education, Thailand. NW thanks Central Scientific Instrument Center (CSIC), Faculty of Science and Technology, Thammasat University, Thailand.

PY - 2016/6/1

Y1 - 2016/6/1

N2 - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]− species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]− resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.

AB - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]− species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]− resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.

KW - Fe(II) coordination frameworks

KW - Self-interpenetrate

KW - AgI ⋯ AgI

KW - Magnetic properties

UR - https://www.scopus.com/pages/publications/84964981914

U2 - 10.1016/j.inoche.2016.04.005

DO - 10.1016/j.inoche.2016.04.005

M3 - Article

SN - 1387-7003

VL - 68

SP - 80

EP - 84

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Two novel self-interpenetrating 3D iron(II) coordination frameworks: synthesis, spectroscopic and structural characterizations with magnetic properties

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Keywords

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