Two novel self-interpenetrating 3D iron(II) coordination frameworks: synthesis, spectroscopic and structural characterizations with magnetic properties

Zouaoui Setifi, Abderazzak Addala, Jun Tao, Nanthawat Wannarit, Christopher Glidewell, Fatima Setifi, Sujittra Youngme

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3] species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2] resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.
Original languageEnglish
Pages (from-to)80-84
Number of pages5
JournalInorganic Chemistry Communications
Volume68
Early online date16 Apr 2016
DOIs
Publication statusPublished - 1 Jun 2016

Keywords

  • Fe(II) coordination frameworks
  • Self-interpenetrate
  • AgI ⋯ AgI
  • Magnetic properties

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