Tuning the reactivity of oxide surfaces by charge-accepting adsorbates

Yuemin Wang; Xinyu Xia; Alexander Urban; Hengshan Qiu; Jennifer Strunk; Bernd Meyer; Martin Muhler; Christof Wöll

doi:10.1002/anie.200702815

Tuning the reactivity of oxide surfaces by charge-accepting adsorbates

Yuemin Wang^*, Xinyu Xia, Alexander Urban, Hengshan Qiu, Jennifer Strunk, Bernd Meyer, Martin Muhler, Christof Wöll

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Bridging the materials and pressure gaps : The adsorption of CO on ZnO surfaces becomes much stronger in the presence of preadsorbed CO₂ (see picture; O red, Zn gray, C green). The increased strength of the interaction between CO and polycrystalline ZnO powder originates from the formation of tridentate carbonate species on the mixed-terminated (1010) surfaces, which increase the Lewis acidity of neighboring Zn²⁺ cations. (Figure Presented).

Original language	English
Pages (from-to)	7315-7318
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	38
DOIs	https://doi.org/10.1002/anie.200702815
Publication status	Published - 10 Oct 2007

Keywords

Ab initio calculations
Heterogeneous catalysis
Microcalorimetry
Vibrational spectroscopy
Zinc oxide

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10.1002/anie.200702815

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abstract = "Bridging the materials and pressure gaps : The adsorption of CO on ZnO surfaces becomes much stronger in the presence of preadsorbed CO2 (see picture; O red, Zn gray, C green). The increased strength of the interaction between CO and polycrystalline ZnO powder originates from the formation of tridentate carbonate species on the mixed-terminated (1010) surfaces, which increase the Lewis acidity of neighboring Zn2+ cations. (Figure Presented).",

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AU - Wang, Yuemin

AU - Xia, Xinyu

AU - Urban, Alexander

AU - Qiu, Hengshan

AU - Strunk, Jennifer

AU - Meyer, Bernd

AU - Muhler, Martin

AU - Wöll, Christof

PY - 2007/10/10

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N2 - Bridging the materials and pressure gaps : The adsorption of CO on ZnO surfaces becomes much stronger in the presence of preadsorbed CO2 (see picture; O red, Zn gray, C green). The increased strength of the interaction between CO and polycrystalline ZnO powder originates from the formation of tridentate carbonate species on the mixed-terminated (1010) surfaces, which increase the Lewis acidity of neighboring Zn2+ cations. (Figure Presented).

AB - Bridging the materials and pressure gaps : The adsorption of CO on ZnO surfaces becomes much stronger in the presence of preadsorbed CO2 (see picture; O red, Zn gray, C green). The increased strength of the interaction between CO and polycrystalline ZnO powder originates from the formation of tridentate carbonate species on the mixed-terminated (1010) surfaces, which increase the Lewis acidity of neighboring Zn2+ cations. (Figure Presented).

KW - Ab initio calculations

KW - Heterogeneous catalysis

KW - Microcalorimetry

KW - Vibrational spectroscopy

KW - Zinc oxide

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M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 38

ER -

Tuning the reactivity of oxide surfaces by charge-accepting adsorbates

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Keywords

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