Tuning the nitric oxide release behavior of amino functionalized HKUST-1

K. Peikert; L.J. McCormick; D. Cattaneo; M.J. Duncan; F. Hoffmann; A.H. Khan; M. Bertmer; R.E. Morris; M. Fröba

doi:10.1016/j.micromeso.2015.06.020

Tuning the nitric oxide release behavior of amino functionalized HKUST-1

K. Peikert, L.J. McCormick, D. Cattaneo, M.J. Duncan, F. Hoffmann, A.H. Khan, M. Bertmer, R.E. Morris, M. Fröba

Research output: Contribution to journal › Article › peer-review

Abstract

Four new secondary amino functionalized trimesic acid ligands (H₃RNHbtc, R=Me, Et, ⁿPr, and ⁱPr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu₃(btc)₂.

Original language	English
Pages (from-to)	118-126
Journal	Microporous and Mesoporous Materials
Volume	216
Early online date	25 Jun 2015
DOIs	https://doi.org/10.1016/j.micromeso.2015.06.020
Publication status	Published - 1 Nov 2015

Keywords

Metal-organic framework
HKUST-1
Amino functionalized HKUST-1
Nitric oxide release
NONOate

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10.1016/j.micromeso.2015.06.020

Cite this

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title = "Tuning the nitric oxide release behavior of amino functionalized HKUST-1",

abstract = "Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.",

keywords = "Metal-organic framework, HKUST-1, Amino functionalized HKUST-1, Nitric oxide release, NONOate",

author = "K. Peikert and L.J. McCormick and D. Cattaneo and M.J. Duncan and F. Hoffmann and A.H. Khan and M. Bertmer and R.E. Morris and M. Fr{\"o}ba",

note = "We thank the Deutsche Forschungsgemeinschaft (DFG: Fr 1372/18-2) for supporting this work as part of the priority program 1362 (porous metal-organic framework).",

year = "2015",

month = nov,

day = "1",

doi = "10.1016/j.micromeso.2015.06.020",

language = "English",

volume = "216",

pages = "118--126",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

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T1 - Tuning the nitric oxide release behavior of amino functionalized HKUST-1

AU - Peikert, K.

AU - McCormick, L.J.

AU - Cattaneo, D.

AU - Duncan, M.J.

AU - Hoffmann, F.

AU - Khan, A.H.

AU - Bertmer, M.

AU - Morris, R.E.

AU - Fröba, M.

N1 - We thank the Deutsche Forschungsgemeinschaft (DFG: Fr 1372/18-2) for supporting this work as part of the priority program 1362 (porous metal-organic framework).

PY - 2015/11/1

Y1 - 2015/11/1

N2 - Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.

AB - Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.

KW - Metal-organic framework

KW - HKUST-1

KW - Amino functionalized HKUST-1

KW - Nitric oxide release

KW - NONOate

UR - http://www.sciencedirect.com/science/article/pii/S1387181115003479#appd001

UR - https://www.scopus.com/pages/publications/84934326013

U2 - 10.1016/j.micromeso.2015.06.020

DO - 10.1016/j.micromeso.2015.06.020

M3 - Article

SN - 1387-1811

VL - 216

SP - 118

EP - 126

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Tuning the nitric oxide release behavior of amino functionalized HKUST-1

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Novel nitric oxide delivery systems for biomedical applications

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Tuning the nitric oxide release behavior of amino functionalized HKUST-1

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Keywords

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Student theses

Novel nitric oxide delivery systems for biomedical applications

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