TY - JOUR
T1 - Tuning the nitric oxide release behavior of amino functionalized HKUST-1
AU - Peikert, K.
AU - McCormick, L.J.
AU - Cattaneo, D.
AU - Duncan, M.J.
AU - Hoffmann, F.
AU - Khan, A.H.
AU - Bertmer, M.
AU - Morris, R.E.
AU - Fröba, M.
N1 - We thank the Deutsche Forschungsgemeinschaft (DFG: Fr 1372/18-2) for supporting this work as part of the priority program 1362 (porous metal-organic framework).
PY - 2015/11/1
Y1 - 2015/11/1
N2 - Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.
AB - Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.
KW - Metal-organic framework
KW - HKUST-1
KW - Amino functionalized HKUST-1
KW - Nitric oxide release
KW - NONOate
UR - http://www.sciencedirect.com/science/article/pii/S1387181115003479#appd001
U2 - 10.1016/j.micromeso.2015.06.020
DO - 10.1016/j.micromeso.2015.06.020
M3 - Article
SN - 1387-1811
VL - 216
SP - 118
EP - 126
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
ER -