Tuning the nitric oxide release behavior of amino functionalized HKUST-1

K. Peikert, L.J. McCormick, D. Cattaneo, M.J. Duncan, F. Hoffmann, A.H. Khan, M. Bertmer, R.E. Morris, M. Fröba

Research output: Contribution to journalArticlepeer-review

39 Citations (Scopus)

Abstract

Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R=Me, Et, n Pr, and i Pr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.

Original languageEnglish
Pages (from-to)118-126
JournalMicroporous and Mesoporous Materials
Volume216
Early online date25 Jun 2015
DOIs
Publication statusPublished - 1 Nov 2015

Keywords

  • Metal-organic framework
  • HKUST-1
  • Amino functionalized HKUST-1
  • Nitric oxide release
  • NONOate

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