Tris(ethylenediamine)zinc(II) hexafluoridosilicate

Yang Li; Qi Shi; Alexandra M. Z. Slawin; J. Derek Woollins; Jinxiang Dong

doi:10.1107/S1600536809045693

Tris(ethylenediamine)zinc(II) hexafluoridosilicate

Yang Li, Qi Shi, Alexandra M. Z. Slawin, J. Derek Woollins, Jinxiang Dong

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms.

Original language	English
Pages (from-to)	M1522-U277
Number of pages	7
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	65
Issue number	12
DOIs	https://doi.org/10.1107/S1600536809045693
Publication status	Published - Dec 2009

Keywords

Crystal

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10.1107/S1600536809045693

2009ActaCrystE65 m1522
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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title = "Tris(ethylenediamine)zinc(II) hexafluoridosilicate",

abstract = "The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms.",

keywords = "Crystal",

author = "Yang Li and Qi Shi and Slawin, \{Alexandra M. Z.\} and Woollins, \{J. Derek\} and Jinxiang Dong",

year = "2009",

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doi = "10.1107/S1600536809045693",

language = "English",

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journal = "Acta Crystallographica. Section E, Structure reports online",

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T1 - Tris(ethylenediamine)zinc(II) hexafluoridosilicate

AU - Li, Yang

AU - Shi, Qi

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

AU - Dong, Jinxiang

PY - 2009/12

Y1 - 2009/12

N2 - The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms.

AB - The title compound, [Zn(C2H8N2)(3)](SiF6), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The Zn-II ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6](2-) anions and the ethylenediamine NH hydrogen atoms.

KW - Crystal

UR - https://www.scopus.com/pages/publications/72049092662

U2 - 10.1107/S1600536809045693

DO - 10.1107/S1600536809045693

M3 - Article

SN - 1600-5368

VL - 65

SP - M1522-U277

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

IS - 12

ER -

Tris(ethylenediamine)zinc(II) hexafluoridosilicate

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