Tris[4-(4-nitrophenyl)-3-aza-3-butenyllamine: pi-stacked chains of hydrogen-bonded R-2(2)(26) dimers

C  Glidewell; J N  Low; J M S  Skakle; J L  Wardell

doi:10.1107/S0108270104033141

Tris[4-(4-nitrophenyl)-3-aza-3-butenyllamine: pi-stacked chains of hydrogen-bonded R-2(2)(26) dimers

C Glidewell, J N Low, J M S Skakle, J L Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	61
DOIs	https://doi.org/10.1107/S0108270104033141
Publication status	Published - Feb 2005

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title = "Tris[4-(4-nitrophenyl)-3-aza-3-butenyllamine: pi-stacked chains of hydrogen-bonded R-2(2)(26) dimers",

abstract = "In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.",

author = "C Glidewell and Low, \{J N\} and Skakle, \{J M S\} and Wardell, \{J L\}",

year = "2005",

month = feb,

doi = "10.1107/S0108270104033141",

language = "English",

volume = "61",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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T1 - Tris[4-(4-nitrophenyl)-3-aza-3-butenyllamine: pi-stacked chains of hydrogen-bonded R-2(2)(26) dimers

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2005/2

Y1 - 2005/2

N2 - In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

AB - In the title compound [alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethane- diaminel, C27H27N7O6, the three independent NCH2CH2N= CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R-2(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01 (1) over bar) sheets.

UR - https://www.scopus.com/pages/publications/30944446236

U2 - 10.1107/S0108270104033141

DO - 10.1107/S0108270104033141

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 61

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Tris[4-(4-nitrophenyl)-3-aza-3-butenyllamine: pi-stacked chains of hydrogen-bonded R-2(2)(26) dimers

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