Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions

Z. Setifi; F. Setifi; H. Boughzala; A. Beghidja; C. Glidewell

doi:10.1107/S2053229614008092

Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions

Z. Setifi
, F. Setifi
, H. Boughzala
, A. Beghidja
, C. Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Fe(C₁₀H₈N₂)₃](C₉H₅N₄O)₂·2H₂O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C₂²(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.

Original language	English
Pages (from-to)	465-469
Number of pages	5
Journal	Acta Crystallographica Section C Structural Chemistry
Volume	70
Issue number	5
DOIs	https://doi.org/10.1107/S2053229614008092
Publication status	Published - 1 May 2014

Keywords

Crystal structure
Hydrogen bonding
Tris(2,2′-bipyridine)iron(II)
1,1,3,3-tetracyano-2-ethoxypropenide
Interpenetrating chiral frameworks
Polynitrile ligands
Spin crossover (SCO) phenomenon

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Glidewell_2014_SC_Tris
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@article{228f2208d72c4dc892ff7de67e57e738,

title = "Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions",

abstract = "In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.",

keywords = "Crystal structure, Hydrogen bonding, Tris(2,2′-bipyridine)iron(II), 1,1,3,3-tetracyano-2-ethoxypropenide, Interpenetrating chiral frameworks, Polynitrile ligands, Spin crossover (SCO) phenomenon",

author = "Z. Setifi and F. Setifi and H. Boughzala and A. Beghidja and C. Glidewell",

note = "The authors acknowledge the Algerian Ministry of Higher Education and Scientific Research, the Algerian Directorate-General for Scientific Research and Technological Development, and Ferhat Abbas Setif 1 University for financial support.",

year = "2014",

month = may,

day = "1",

doi = "10.1107/S2053229614008092",

language = "English",

volume = "70",

pages = "465--469",

journal = "Acta Crystallographica Section C Structural Chemistry",

issn = "2053-2296",

publisher = "John Wiley \& Sons, Ltd",

number = "5",

}

TY - JOUR

T1 - Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate

T2 - chiral hydrogen-bonded frameworks interpenetrate in three dimensions

AU - Setifi, Z.

AU - Setifi, F.

AU - Boughzala, H.

AU - Beghidja, A.

AU - Glidewell, C.

N1 - The authors acknowledge the Algerian Ministry of Higher Education and Scientific Research, the Algerian Directorate-General for Scientific Research and Technological Development, and Ferhat Abbas Setif 1 University for financial support.

PY - 2014/5/1

Y1 - 2014/5/1

N2 - In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.

AB - In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.

KW - Crystal structure

KW - Hydrogen bonding

KW - Tris(2,2′-bipyridine)iron(II)

KW - 1,1,3,3-tetracyano-2-ethoxypropenide

KW - Interpenetrating chiral frameworks

KW - Polynitrile ligands

KW - Spin crossover (SCO) phenomenon

UR - https://www.scopus.com/pages/publications/84905450034

U2 - 10.1107/S2053229614008092

DO - 10.1107/S2053229614008092

M3 - Article

AN - SCOPUS:84905450034

SN - 2053-2296

VL - 70

SP - 465

EP - 469

JO - Acta Crystallographica Section C Structural Chemistry

JF - Acta Crystallographica Section C Structural Chemistry

IS - 5

ER -

Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions

Abstract

Keywords

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