TY - JOUR
T1 - Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate
T2 - chiral hydrogen-bonded frameworks interpenetrate in three dimensions
AU - Setifi, Z.
AU - Setifi, F.
AU - Boughzala, H.
AU - Beghidja, A.
AU - Glidewell, C.
N1 - The authors acknowledge the Algerian Ministry of Higher Education and Scientific Research, the Algerian Directorate-General for Scientific Research and Technological Development, and Ferhat Abbas Setif 1 University for financial support.
PY - 2014/5/1
Y1 - 2014/5/1
N2 - In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.
AB - In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.
KW - Crystal structure
KW - Hydrogen bonding
KW - Tris(2,2′-bipyridine)iron(II)
KW - 1,1,3,3-tetracyano-2-ethoxypropenide
KW - Interpenetrating chiral frameworks
KW - Polynitrile ligands
KW - Spin crossover (SCO) phenomenon
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84905450034&partnerID=8YFLogxK
U2 - 10.1107/S2053229614008092
DO - 10.1107/S2053229614008092
M3 - Article
AN - SCOPUS:84905450034
SN - 2053-2296
VL - 70
SP - 465
EP - 469
JO - Acta Crystallographica Section C Structural Chemistry
JF - Acta Crystallographica Section C Structural Chemistry
IS - 5
ER -