Tris(1,10-phenanthroline-5,6-dione-kappa N-2,N ')copper(II) bis(perchlorate) 4.5-hydrate

Aliakbar Dehno Khalaji; Alexandra M. Z. Slawin; J. Derek Woollins

doi:10.1107/S1600536807052348

Tris(1,10-phenanthroline-5,6-dione-kappa N-2,N ')copper(II) bis(perchlorate) 4.5-hydrate

Aliakbar Dehno Khalaji, Alexandra M. Z. Slawin, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [Cu(C12H6N2O2)(3)](ClO4)(2) center dot 4.5H(2)O, the Cu-II atom is in a distorted octahedral environment with unequal Cu-N distances, due to the Jahn-Teller elongation of the two Cu-N bonds in trans positions. The crystal studied was an inversion twin..

Original language	English
Number of pages	12
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	63
DOIs	https://doi.org/10.1107/S1600536807052348
Publication status	Published - Nov 2007

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abstract = "In the title compound, [Cu(C12H6N2O2)(3)](ClO4)(2) center dot 4.5H(2)O, the Cu-II atom is in a distorted octahedral environment with unequal Cu-N distances, due to the Jahn-Teller elongation of the two Cu-N bonds in trans positions. The crystal studied was an inversion twin..",

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T1 - Tris(1,10-phenanthroline-5,6-dione-kappa N-2,N ')copper(II) bis(perchlorate) 4.5-hydrate

AU - Khalaji, Aliakbar Dehno

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

PY - 2007/11

Y1 - 2007/11

N2 - In the title compound, [Cu(C12H6N2O2)(3)](ClO4)(2) center dot 4.5H(2)O, the Cu-II atom is in a distorted octahedral environment with unequal Cu-N distances, due to the Jahn-Teller elongation of the two Cu-N bonds in trans positions. The crystal studied was an inversion twin..

AB - In the title compound, [Cu(C12H6N2O2)(3)](ClO4)(2) center dot 4.5H(2)O, the Cu-II atom is in a distorted octahedral environment with unequal Cu-N distances, due to the Jahn-Teller elongation of the two Cu-N bonds in trans positions. The crystal studied was an inversion twin..

KW - COMPLEX

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DO - 10.1107/S1600536807052348

M3 - Article

SN - 1600-5368

VL - 63

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

ER -

Tris(1,10-phenanthroline-5,6-dione-kappa N-2,N ')copper(II) bis(perchlorate) 4.5-hydrate

Abstract

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