Triple-cation perovskite solar cells for visible light communications

Natalie Mica; Rui Bian; Pavlos Manousiadis; Lethy Krishnan Jagadamma; Imam Tavakklolnia; Harald Haas; Graham Turnbull; Ifor David William Samuel

doi:10.1364/PRJ.393647

Triple-cation perovskite solar cells for visible light communications

Natalie Mica, Rui Bian, Pavlos Manousiadis, Lethy Krishnan Jagadamma, Imam Tavakklolnia, Harald Haas, Graham Turnbull, Ifor David William Samuel

Research output: Contribution to journal › Article › peer-review

Abstract

Hybrid perovskite materials are widely researched due to their high absorptivity, inexpensive synthesis, and promise in photovoltaic devices. These materials are also of interest as highly sensitive photodetectors. In this study, their potential for use in visible light communication is explored in a configuration that allows for simultaneous energy and data harvesting. Using a triple-cation material and appropriate device design, a new record data rate for perovskite photodetectors of 56 Mbps and power conversion efficiencies above 20% under white LED illumination are achieved. With this device design, the −3 dB bandwidth is increased by minimizing the dominating time constant of the system. This correlation between the bandwidth and time constant is proved using measurements of time-resolved photoluminescence, transient photovoltage, and device resistance.

Original language	English
Pages (from-to)	A16-A24
Number of pages	9
Journal	Photonics Research
Volume	8
Issue number	8
Early online date	14 Jul 2020
DOIs	https://doi.org/10.1364/PRJ.393647
Publication status	Published - 1 Aug 2020

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10.1364/PRJ.393647Licence: CC BY

Mica-2020-Triple-cation-perovskite-PRJ-8-8-A16-CC
Copyright © 2020 the Author(s). Published by Chinese Laser Press under the terms of the Creative Commons Attribution 4.0 License. Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.https://doi.org/10.1364/PRJ.393647
Final published version, 1.59 MBLicence: CC BY

H2020 MSCA - PHOTOPEROVSKITIES: H2020 MSCA Fellowship 2016 Lethy
Samuel, I. D. W. (PI)
European Commission
1/09/17 → 31/08/19
Project: Fellowship
Equipment Account: Characterisation and Manipulation of Advanced Functional Materials and their Interfaces at the Nanoscale
Samuel, I. D. W. (PI)
EPSRC
1/10/13 → 30/09/23
Project: Standard

Triple cation perovskite solar cells for visible light communications (dataset)
Mica, N. (Creator), BIAN, R. (Creator), Manousiadis, P. (Creator), Krishnan Jagadamma, L. (Creator), TAVAKKOLNIA, I. (Creator), HAAS, H. (Creator), Turnbull, G. (Creator) & Samuel, I. D. W. (Creator), University of St Andrews, 2020
DOI: 10.17630/2bde6593-32d5-47fe-849c-d34c3dabbe58
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title = "Triple-cation perovskite solar cells for visible light communications",

abstract = "Hybrid perovskite materials are widely researched due to their high absorptivity, inexpensive synthesis, and promise in photovoltaic devices. These materials are also of interest as highly sensitive photodetectors. In this study, their potential for use in visible light communication is explored in a configuration that allows for simultaneous energy and data harvesting. Using a triple-cation material and appropriate device design, a new record data rate for perovskite photodetectors of 56 Mbps and power conversion efficiencies above 20% under white LED illumination are achieved. With this device design, the −3 dB bandwidth is increased by minimizing the dominating time constant of the system. This correlation between the bandwidth and time constant is proved using measurements of time-resolved photoluminescence, transient photovoltage, and device resistance.",

author = "Natalie Mica and Rui Bian and Pavlos Manousiadis and {Krishnan Jagadamma}, Lethy and Imam Tavakklolnia and Harald Haas and Graham Turnbull and Samuel, {Ifor David William}",

note = "Funding: UK EPSRC under grant codes EP/L015110/1 and EP/L017008/1. Dr. L. K. Jagadamma acknowledges support from a Marie Sk{\l}odowska-Curie Individual Fellowship (European Commission) (MCIF: No. 745776). Harald Haas acknowledges financial support from the Wolfson Foundation and Royal Society. He also acknowledges financial support by the Engineering and Physical Sciences Research Council (EPSRC) under an Established Career Fellowship grant EP/R007101/1.",

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T1 - Triple-cation perovskite solar cells for visible light communications

AU - Mica, Natalie

AU - Bian, Rui

AU - Manousiadis, Pavlos

AU - Krishnan Jagadamma, Lethy

AU - Tavakklolnia, Imam

AU - Haas, Harald

AU - Turnbull, Graham

AU - Samuel, Ifor David William

N1 - Funding: UK EPSRC under grant codes EP/L015110/1 and EP/L017008/1. Dr. L. K. Jagadamma acknowledges support from a Marie Skłodowska-Curie Individual Fellowship (European Commission) (MCIF: No. 745776). Harald Haas acknowledges financial support from the Wolfson Foundation and Royal Society. He also acknowledges financial support by the Engineering and Physical Sciences Research Council (EPSRC) under an Established Career Fellowship grant EP/R007101/1.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Hybrid perovskite materials are widely researched due to their high absorptivity, inexpensive synthesis, and promise in photovoltaic devices. These materials are also of interest as highly sensitive photodetectors. In this study, their potential for use in visible light communication is explored in a configuration that allows for simultaneous energy and data harvesting. Using a triple-cation material and appropriate device design, a new record data rate for perovskite photodetectors of 56 Mbps and power conversion efficiencies above 20% under white LED illumination are achieved. With this device design, the −3 dB bandwidth is increased by minimizing the dominating time constant of the system. This correlation between the bandwidth and time constant is proved using measurements of time-resolved photoluminescence, transient photovoltage, and device resistance.

AB - Hybrid perovskite materials are widely researched due to their high absorptivity, inexpensive synthesis, and promise in photovoltaic devices. These materials are also of interest as highly sensitive photodetectors. In this study, their potential for use in visible light communication is explored in a configuration that allows for simultaneous energy and data harvesting. Using a triple-cation material and appropriate device design, a new record data rate for perovskite photodetectors of 56 Mbps and power conversion efficiencies above 20% under white LED illumination are achieved. With this device design, the −3 dB bandwidth is increased by minimizing the dominating time constant of the system. This correlation between the bandwidth and time constant is proved using measurements of time-resolved photoluminescence, transient photovoltage, and device resistance.

U2 - 10.1364/PRJ.393647

DO - 10.1364/PRJ.393647

M3 - Article

SN - 2327-9125

VL - 8

SP - A16-A24

JO - Photonics Research

JF - Photonics Research

IS - 8

ER -

Triple-cation perovskite solar cells for visible light communications

Abstract

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Projects

H2020 MSCA - PHOTOPEROVSKITIES: H2020 MSCA Fellowship 2016 Lethy

Equipment Account: Characterisation and Manipulation of Advanced Functional Materials and their Interfaces at the Nanoscale

Datasets

Triple cation perovskite solar cells for visible light communications (dataset)

Cite this