Tricoordinate complexes of lead(II) with innocent Schiff base ligands

J  Parr; A T  Ross; A M Z  Slawin

Tricoordinate complexes of lead(II) with innocent Schiff base ligands

J Parr, A T Ross, A M Z Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of lead(II) perchlorate hydrate with Schiff base ligands resulted in the formation of unexpected complexes wherein the ligand is coordinated in an ''innocent'' fashion. These compounds were characterised by H-1 NMR, IR and single crystal X-ray studies. These reveal an unprecedented binding mode for these ligands, where some of the apparently available binding sites are not used, and the lead(II) displays a low coordination number. (C) 1997 Elsevier Science Ltd.

Original language	English
Pages (from-to)	2765-2770
Number of pages	6
Journal	Polyhedron
Volume	16
Issue number	16
Publication status	Published - 1997

Keywords

lead(II) complexes
innocent Schiff base
crystal structures
low coordination number
CRYSTAL-STRUCTURE
METAL

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title = "Tricoordinate complexes of lead(II) with innocent Schiff base ligands",

abstract = "The interaction of lead(II) perchlorate hydrate with Schiff base ligands resulted in the formation of unexpected complexes wherein the ligand is coordinated in an ''innocent'' fashion. These compounds were characterised by H-1 NMR, IR and single crystal X-ray studies. These reveal an unprecedented binding mode for these ligands, where some of the apparently available binding sites are not used, and the lead(II) displays a low coordination number. (C) 1997 Elsevier Science Ltd.",

keywords = "lead(II) complexes, innocent Schiff base, crystal structures, low coordination number, CRYSTAL-STRUCTURE, METAL",

author = "J Parr and Ross, {A T} and Slawin, {A M Z}",

year = "1997",

language = "English",

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journal = "Polyhedron",

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T1 - Tricoordinate complexes of lead(II) with innocent Schiff base ligands

AU - Parr, J

AU - Ross, A T

AU - Slawin, A M Z

PY - 1997

Y1 - 1997

N2 - The interaction of lead(II) perchlorate hydrate with Schiff base ligands resulted in the formation of unexpected complexes wherein the ligand is coordinated in an ''innocent'' fashion. These compounds were characterised by H-1 NMR, IR and single crystal X-ray studies. These reveal an unprecedented binding mode for these ligands, where some of the apparently available binding sites are not used, and the lead(II) displays a low coordination number. (C) 1997 Elsevier Science Ltd.

AB - The interaction of lead(II) perchlorate hydrate with Schiff base ligands resulted in the formation of unexpected complexes wherein the ligand is coordinated in an ''innocent'' fashion. These compounds were characterised by H-1 NMR, IR and single crystal X-ray studies. These reveal an unprecedented binding mode for these ligands, where some of the apparently available binding sites are not used, and the lead(II) displays a low coordination number. (C) 1997 Elsevier Science Ltd.

KW - lead(II) complexes

KW - innocent Schiff base

KW - crystal structures

KW - low coordination number

KW - CRYSTAL-STRUCTURE

KW - METAL

M3 - Article

SN - 0277-5387

VL - 16

SP - 2765

EP - 2770

JO - Polyhedron

JF - Polyhedron

IS - 16

ER -

Tricoordinate complexes of lead(II) with innocent Schiff base ligands

Abstract

Keywords

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