Tricoordinate complexes of lead(II) with innocent Schiff base ligands

J Parr, A T Ross, A M Z Slawin

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The interaction of lead(II) perchlorate hydrate with Schiff base ligands resulted in the formation of unexpected complexes wherein the ligand is coordinated in an ''innocent'' fashion. These compounds were characterised by H-1 NMR, IR and single crystal X-ray studies. These reveal an unprecedented binding mode for these ligands, where some of the apparently available binding sites are not used, and the lead(II) displays a low coordination number. (C) 1997 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)2765-2770
Number of pages6
JournalPolyhedron
Volume16
Issue number16
Publication statusPublished - 1997

Keywords

  • lead(II) complexes
  • innocent Schiff base
  • crystal structures
  • low coordination number
  • CRYSTAL-STRUCTURE
  • METAL

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