Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes

J.M. Rawson; L. Donato; E. Zysman-Colman

doi:10.1039/c4ce00980k

Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes

J.M. Rawson, L. Donato, E. Zysman-Colman

Research output: Contribution to journal › Article › peer-review

Abstract

Despite the differing size of the Cl⁻ and PF₆⁻ counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)₂(btl)]Cl, [1]Cl, and [Ir(dFphtl)₂(btl)]PF₆, [1]PF₆, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.

Original language	English
Pages (from-to)	8531-8536
Number of pages	6
Journal	CrystEngComm
Volume	16
Issue number	36
Early online date	22 Jul 2014
DOIs	https://doi.org/10.1039/c4ce00980k
Publication status	Published - 28 Sept 2014

Access to Document

10.1039/c4ce00980k

revised_ms
© Royal Society of Chemistry 2014. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4CE00980K
Accepted author manuscript, 746 KB

Cite this

@article{92bd298148fa486b99a676780936a9b4,

title = "Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes",

abstract = "Despite the differing size of the Cl− and PF6− counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)2(btl)]Cl, [1]Cl, and [Ir(dFphtl)2(btl)]PF6, [1]PF6, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.",

author = "J.M. Rawson and L. Donato and E. Zysman-Colman",

year = "2014",

month = sep,

day = "28",

doi = "10.1039/c4ce00980k",

language = "English",

volume = "16",

pages = "8531--8536",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "36",

}

TY - JOUR

T1 - Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes

AU - Rawson, J.M.

AU - Donato, L.

AU - Zysman-Colman, E.

PY - 2014/9/28

Y1 - 2014/9/28

N2 - Despite the differing size of the Cl− and PF6− counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)2(btl)]Cl, [1]Cl, and [Ir(dFphtl)2(btl)]PF6, [1]PF6, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.

AB - Despite the differing size of the Cl− and PF6− counter-ions, the structures of the heteroleptic iridium(III) complexes, [Ir(dFphtl)2(btl)]Cl, [1]Cl, and [Ir(dFphtl)2(btl)]PF6, [1]PF6, (where dFphtl = 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole and btl = 1,1′-dibenzyl-4,4′-bi-1H-1,2,3-triazolyl) are found to exhibit similar morphologies in which both structures adopt hydrogen-bonded networks driven by the hydrogen-bond donor and acceptor demands of the triazole functional group. The triazole thus can be used as a supramolecular synthon to control the internuclear distance in the solid-state.

UR - http://www.rsc.org/suppdata/ce/c4/c4ce00980k/c4ce00980k1.cif

UR - https://www.scopus.com/pages/publications/84906232131

U2 - 10.1039/c4ce00980k

DO - 10.1039/c4ce00980k

M3 - Article

AN - SCOPUS:84906232131

SN - 1466-8033

VL - 16

SP - 8531

EP - 8536

JO - CrystEngComm

JF - CrystEngComm

IS - 36

ER -

Triazole-directed hydrogen-bonded structures of cationic iridium(III) complexes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this