Projects per year
Abstract
The behavior of the Pm (3) over barm-R (3) over barc phase transition in LaAlO3 (T-C=813 K from differential scanning calorimetry measurements) has been studied using temperature-dependent measurements of the crystal structure, dielectric relaxation, specific heat, birefringence, and the frequencies of the two soft modes (via Raman spectroscopy). While all these experiments show behavior near T-C consistent with a second-order Landau transition, there is extensive evidence for additional anomalous behavior below 730 K. Below this temperature, the two soft mode frequencies are not proportional to each other, the spontaneous strain is not proportional to the square of the AlO6 rotation angle, and anomalies are seen in the birefringence. Twin domains, which are mobile above 730 K, are frozen below 730 K. These anomalies are consistent with biquadratic coupling between the primary order parameter of the transition (AlO6 rotation) and a second process. From the dielectric results, which indicate a smooth but rapid increase in conductivity in the temperature range 500-800 K, we propose that this second process is hopping of intrinsic oxygen vacancies. These vacancies are essentially static below 730 K and dynamically disordered above 730 K. The interaction between static vacancies and the displacive phase transition is unfavorable. A similar anomaly may be observed in other aluminate perovskites undergoing the same transition.
Original language | English |
---|---|
Article number | 054110 |
Pages (from-to) | - |
Number of pages | 17 |
Journal | Physical Review. B, Condensed matter and materials physics |
Volume | 72 |
Issue number | 5 |
DOIs | |
Publication status | Published - Aug 2005 |
Keywords
- ORDER-PARAMETER SATURATION
- CUBIC PHASE-TRANSITION
- POWDER DIFFRACTION
- DOMAIN-STRUCTURE
- LANDAU THEORY
- PEROVSKITES
- STRAIN
- BIREFRINGENCE
- OCTAHEDRA
- EXPANSION
Fingerprint
Dive into the research topics of 'Transformation processes in LaAlO3: Neutron diffraction, dielectric, thermal, optical, and Raman studies'. Together they form a unique fingerprint.Projects
- 1 Finished
-
Royal Society Fellowship 516002.K5799/je: Royal Society Fellowship 516002.K5799/je
Morrison, F. (PI)
1/08/06 → 30/09/09
Project: Fellowship