Abstract
A survey of catalysts able to mediate the transesterification/acylation reaction is presented. Metal and organic catalysts are capable of facilitating this important transformation.
1 Introduction
2 Transesterification Reactions Catalyzed by Lewis Acids
2.1 Lanthanide (Sm) Catalysis
2.2 Tin Catalysis
2.3 Indium Catalysis
2.4 Yttrium Catalysis
3 Transesterification Reactions Catalyzed by Nucleophilic Catalysts
3.1 Superbase-Catalyzed Transesterification of Esters with Alcohols
3.2 Nucleophilic N-Heterocyclic Carbene (NHC) Catalysis
4 Conclusions.
| Original language | English |
|---|---|
| Pages (from-to) | 971-985 |
| Number of pages | 15 |
| Journal | Synthesis |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 6 May 2004 |
Keywords
- transesterifications
- acylations
- catalysis
- carbenes
- esters
- DYNAMIC KINETIC RESOLUTION
- N-HETEROCYCLIC CARBENES
- EFFICIENT ESTERIFICATION REACTION
- HIGHLY SELECTIVE ACYLATION
- MUKAIYAMA-ALDOL REACTION
- BAYLIS-HILLMAN REACTION
- SECONDARY ALCOHOLS
- ENOL ESTERS
- LIVING POLYMERIZATION
- ASYMMETRIC CATALYSIS
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