Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

R  Singh; R M  Kissling; M A  Letellier; Steven Patrick Nolan

doi:10.1021/jo035431p

Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

R Singh
, R M Kissling
, M A Letellier
, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

Original language	English
Pages (from-to)	209-212
Number of pages	4
Journal	The Journal of Organic Chemistry
Volume	69
Issue number	1
DOIs	https://doi.org/10.1021/jo035431p
Publication status	Published - 9 Jan 2004

Keywords

HIGHLY SELECTIVE ACYLATION
OLEFIN METATHESIS
LIVING POLYMERIZATION
NUCLEOPHILIC CARBENES
STABLE CARBENES
ENOL ESTERS
LIGANDS
COMPLEXES
CHEMIE

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title = "Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts",

abstract = "N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.",

keywords = "HIGHLY SELECTIVE ACYLATION, OLEFIN METATHESIS, LIVING POLYMERIZATION, NUCLEOPHILIC CARBENES, STABLE CARBENES, ENOL ESTERS, LIGANDS, COMPLEXES, CHEMIE",

author = "R Singh and Kissling, \{R M\} and Letellier, \{M A\} and Nolan, \{Steven Patrick\}",

year = "2004",

month = jan,

day = "9",

doi = "10.1021/jo035431p",

language = "English",

volume = "69",

pages = "209--212",

journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society (ACS)",

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T1 - Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

AU - Singh, R

AU - Kissling, R M

AU - Letellier, M A

AU - Nolan, Steven Patrick

PY - 2004/1/9

Y1 - 2004/1/9

N2 - N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

AB - N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

KW - HIGHLY SELECTIVE ACYLATION

KW - OLEFIN METATHESIS

KW - LIVING POLYMERIZATION

KW - NUCLEOPHILIC CARBENES

KW - STABLE CARBENES

KW - ENOL ESTERS

KW - LIGANDS

KW - COMPLEXES

KW - CHEMIE

UR - https://www.scopus.com/pages/publications/0347361511

U2 - 10.1021/jo035431p

DO - 10.1021/jo035431p

M3 - Article

SN - 0022-3263

VL - 69

SP - 209

EP - 212

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 1

ER -

Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

Abstract

Keywords

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