Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

R  Singh; R M  Kissling; M A  Letellier; Steven Patrick Nolan

doi:10.1021/jo035431p

Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

R Singh, R M Kissling, M A Letellier, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

183 Citations (Scopus)

Abstract

N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

Original language	English
Pages (from-to)	209-212
Number of pages	4
Journal	The Journal of Organic Chemistry
Volume	69
Issue number	1
DOIs	https://doi.org/10.1021/jo035431p
Publication status	Published - 9 Jan 2004

Keywords

HIGHLY SELECTIVE ACYLATION
OLEFIN METATHESIS
LIVING POLYMERIZATION
NUCLEOPHILIC CARBENES
STABLE CARBENES
ENOL ESTERS
LIGANDS
COMPLEXES
CHEMIE

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abstract = "N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.",

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author = "R Singh and Kissling, {R M} and Letellier, {M A} and Nolan, {Steven Patrick}",

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AU - Kissling, R M

AU - Letellier, M A

AU - Nolan, Steven Patrick

PY - 2004/1/9

Y1 - 2004/1/9

N2 - N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

AB - N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.

KW - HIGHLY SELECTIVE ACYLATION

KW - OLEFIN METATHESIS

KW - LIVING POLYMERIZATION

KW - NUCLEOPHILIC CARBENES

KW - STABLE CARBENES

KW - ENOL ESTERS

KW - LIGANDS

KW - COMPLEXES

KW - CHEMIE

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DO - 10.1021/jo035431p

M3 - Article

SN - 0022-3263

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SP - 209

EP - 212

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 1

ER -

Transesterification/acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts

Abstract

Keywords

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