trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate

Alexandra M. Z. Slawin; Paul G. Waddell; J. Derek Woollins

doi:10.1107/S1600536811016849

trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate

Alexandra M. Z. Slawin, Paul G. Waddell, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Both the platininum complex and the solvent molecule of the title compound, [PtBr2(C18H15P)(2)]center dot CHCl3, are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl3 molecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.

Original language	English
Pages (from-to)	M722-U777
Number of pages	8
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	67
DOIs	https://doi.org/10.1107/S1600536811016849
Publication status	Published - Jun 2011

Keywords

TRANS-INFLUENCE

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10.1107/S1600536811016849

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title = "trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate",

abstract = "Both the platininum complex and the solvent molecule of the title compound, [PtBr2(C18H15P)(2)]center dot CHCl3, are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl3 molecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.",

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author = "Slawin, {Alexandra M. Z.} and Waddell, {Paul G.} and Woollins, {J. Derek}",

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AU - Slawin, Alexandra M. Z.

AU - Waddell, Paul G.

AU - Woollins, J. Derek

PY - 2011/6

Y1 - 2011/6

N2 - Both the platininum complex and the solvent molecule of the title compound, [PtBr2(C18H15P)(2)]center dot CHCl3, are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl3 molecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.

AB - Both the platininum complex and the solvent molecule of the title compound, [PtBr2(C18H15P)(2)]center dot CHCl3, are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl3 molecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.

KW - TRANS-INFLUENCE

U2 - 10.1107/S1600536811016849

DO - 10.1107/S1600536811016849

M3 - Article

SN - 1600-5368

VL - 67

SP - M722-U777

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

ER -

trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate

Abstract

Keywords

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