trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

J H  Aupers; G  Ferguson; C  Glidewell; J N  Low; J L  Wardell

trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

J H Aupers, G Ferguson, C Glidewell, J N Low, J L Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) Angstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is also very short [1.744 (4) Angstrom]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a CD H ... O hydrogen bond.

Original language	English
Pages (from-to)	945-947
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	56
Publication status	Published - Aug 2000

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@article{7df1c60bae3044f8921c9357457317ff,

title = "trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate",

abstract = "Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) Angstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is also very short [1.744 (4) Angstrom]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a CD H ... O hydrogen bond.",

author = "Aupers, \{J H\} and G Ferguson and C Glidewell and Low, \{J N\} and Wardell, \{J L\}",

year = "2000",

month = aug,

language = "English",

volume = "56",

pages = "945--947",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

AU - Aupers, J H

AU - Ferguson, G

AU - Glidewell, C

AU - Low, J N

AU - Wardell, J L

PY - 2000/8

Y1 - 2000/8

N2 - Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) Angstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is also very short [1.744 (4) Angstrom]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a CD H ... O hydrogen bond.

AB - Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) Angstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is also very short [1.744 (4) Angstrom]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a CD H ... O hydrogen bond.

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 56

SP - 945

EP - 947

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

Abstract

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