trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

J H Aupers, G Ferguson, C Glidewell, J N Low, J L Wardell

Research output: Contribution to journalArticlepeer-review


Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) Angstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is also very short [1.744 (4) Angstrom]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a CD H ... O hydrogen bond.

Original languageEnglish
Pages (from-to)945-947
Number of pages3
JournalActa Crystallographica Section C-Crystal Structure Communications
Publication statusPublished - Aug 2000


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