TiO2-(B) Nanotubes as Negative Electrodes for  Rechrgeable Lithium Batteries

G Armstrong; A. R. Armstrong; C Canales; Peter George Bruce

doi:10.1149/1.2162327

TiO₂-(B) Nanotubes as Negative Electrodes for Rechrgeable Lithium Batteries

G Armstrong, A. R. Armstrong, C Canales, Peter George Bruce

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Abstract

TiO2 (B) nanotubes were investigated as anodes for rechargeable lithium batteries. They can accommodate up to 338 mAh g(-1) of charge, equivalent to Li1.01TiO2 (B) at a potential of similar to 1.5 V vs Li+ (1 M)/Li. Rate capability is good with a capacity of 95 mAh g(-1) at 2000 mA g(-1) (21C). Capacity fade is 0.16% per cycle compared with 0.10% for the corresponding nanowires. There is an irreversible capacity loss of 29% on the first cycle but thereafter charge/discharge efficiency is close to 100%. (c) 2006 The Electrochemical Society.

Original language	English
Pages (from-to)	A139-A143
Number of pages	5
Journal	Electrochemical and Solid-State Letters
Volume	9
DOIs	https://doi.org/10.1149/1.2162327
Publication status	Published - 2006

Keywords

TIO2-B NANOWIRES
INTERCALATION
LI4TI5O12
INSERTION
CAPABILITY
CELLS

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title = "TiO2-(B) Nanotubes as Negative Electrodes for Rechrgeable Lithium Batteries",

abstract = "TiO2 (B) nanotubes were investigated as anodes for rechargeable lithium batteries. They can accommodate up to 338 mAh g(-1) of charge, equivalent to Li1.01TiO2 (B) at a potential of similar to 1.5 V vs Li+ (1 M)/Li. Rate capability is good with a capacity of 95 mAh g(-1) at 2000 mA g(-1) (21C). Capacity fade is 0.16\% per cycle compared with 0.10\% for the corresponding nanowires. There is an irreversible capacity loss of 29\% on the first cycle but thereafter charge/discharge efficiency is close to 100\%. (c) 2006 The Electrochemical Society.",

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AU - Armstrong, G

AU - Armstrong, A. R.

AU - Canales, C

AU - Bruce, Peter George

PY - 2006

Y1 - 2006

N2 - TiO2 (B) nanotubes were investigated as anodes for rechargeable lithium batteries. They can accommodate up to 338 mAh g(-1) of charge, equivalent to Li1.01TiO2 (B) at a potential of similar to 1.5 V vs Li+ (1 M)/Li. Rate capability is good with a capacity of 95 mAh g(-1) at 2000 mA g(-1) (21C). Capacity fade is 0.16% per cycle compared with 0.10% for the corresponding nanowires. There is an irreversible capacity loss of 29% on the first cycle but thereafter charge/discharge efficiency is close to 100%. (c) 2006 The Electrochemical Society.

AB - TiO2 (B) nanotubes were investigated as anodes for rechargeable lithium batteries. They can accommodate up to 338 mAh g(-1) of charge, equivalent to Li1.01TiO2 (B) at a potential of similar to 1.5 V vs Li+ (1 M)/Li. Rate capability is good with a capacity of 95 mAh g(-1) at 2000 mA g(-1) (21C). Capacity fade is 0.16% per cycle compared with 0.10% for the corresponding nanowires. There is an irreversible capacity loss of 29% on the first cycle but thereafter charge/discharge efficiency is close to 100%. (c) 2006 The Electrochemical Society.

KW - TIO2-B NANOWIRES

KW - INTERCALATION

KW - LI4TI5O12

KW - INSERTION

KW - CAPABILITY

KW - CELLS

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ER -

TiO₂-(B) Nanotubes as Negative Electrodes for Rechrgeable Lithium Batteries

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Keywords

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