Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3

Xiaolong He; Xinyuan Zhang; Bifa Ji; Wenjiao Yao; Philip Lightfoot; Yongbing Tang

doi:10.1039/d1cc00085c

Tilting and twisting in a novel perovzalate, K₃NaMn(C₂O₄)₃

Xiaolong He, Xinyuan Zhang, Bifa Ji, Wenjiao Yao^*, Philip Lightfoot^*, Yongbing Tang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.

Original language	English
Pages (from-to)	2567-2570
Journal	Chemical Communications
Volume	57
Issue number	20
Early online date	4 Feb 2021
DOIs	https://doi.org/10.1039/d1cc00085c
Publication status	Published - 11 Mar 2021

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10.1039/d1cc00085c

He_2021_CC_Tilting_AAM
Copyright © 2021 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D1CC00085C
Accepted author manuscript, 613 KB

Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3 (dataset)
He, X. (Creator), Zhang, X. (Creator), Ji, B. (Creator), Yao, W. (Creator), Lightfoot, P. (Creator) & Tang, Y. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc23kdps
Dataset

Cite this

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title = "Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3",

abstract = "In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique {\textquoteleft}doubly-interpenetrated{\textquoteright} perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare {\textquoteleft}twisted{\textquoteright} conformation.",

author = "Xiaolong He and Xinyuan Zhang and Bifa Ji and Wenjiao Yao and Philip Lightfoot and Yongbing Tang",

note = "We acknowledge support from the National Natural Science Foundation of China (22005329, 52061160484, 51822210, 51972329), Newton International Fellowships Alumni 2018/2019 (AL\180020, AL\191011), Key Area Research and Development Program of Guangdong Province (2019B090914003), Shenzhen Science and Technology Planning Project (No. JCYJ20180507182512042, JCYJ20190807172001755, JCYJ20200109115624923), and Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2019A1515011902, 2019TX05L389).",

year = "2021",

month = mar,

day = "11",

doi = "10.1039/d1cc00085c",

language = "English",

volume = "57",

pages = "2567--2570",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

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TY - JOUR

T1 - Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3

AU - He, Xiaolong

AU - Zhang, Xinyuan

AU - Ji, Bifa

AU - Yao, Wenjiao

AU - Lightfoot, Philip

AU - Tang, Yongbing

N1 - We acknowledge support from the National Natural Science Foundation of China (22005329, 52061160484, 51822210, 51972329), Newton International Fellowships Alumni 2018/2019 (AL\180020, AL\191011), Key Area Research and Development Program of Guangdong Province (2019B090914003), Shenzhen Science and Technology Planning Project (No. JCYJ20180507182512042, JCYJ20190807172001755, JCYJ20200109115624923), and Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2019A1515011902, 2019TX05L389).

PY - 2021/3/11

Y1 - 2021/3/11

N2 - In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.

AB - In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.

U2 - 10.1039/d1cc00085c

DO - 10.1039/d1cc00085c

M3 - Article

SN - 1359-7345

VL - 57

SP - 2567

EP - 2570

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3

Abstract

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Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3 (dataset)

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Tilting and twisting in a novel perovzalate, K₃NaMn(C₂O₄)₃