Through Space Interaction of tethered groups in diphospha peri-substituted naphthalenes

Petr Kilian; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1080/10426500490427826

Through Space Interaction of tethered groups in diphospha peri-substituted naphthalenes

Petr Kilian, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

NMR properties of 1,8-diphosphanaphthalenes with prerequisites for strong through-space interaction were studied. The exceptional magnitude of (4)J(PP) 246 Hz was found in Nap[P(NMe2)(2)][P(OMe)(NMe2)] (Nap = naphthalene-1,8-diyl). The P-III, P-V mixed valence systems Nap[P(E)(OMe)(2)][P(OMe)(2)] (E = O, S, Se) show much lower magnitudes of through-space interaction than expected.

Original language	English
Pages (from-to)	999-1002
Number of pages	4
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	179
Issue number	4-5
DOIs	https://doi.org/10.1080/10426500490427826
Publication status	Published - Apr 2004

Keywords

chalcogenides
phosphorus
strained molecules
P-III
1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE
COORDINATION
DERIVATIVES

Access to Document

10.1080/10426500490427826

Cite this

@article{c4ae73477c414989acd77bc0c2f13723,

title = "Through Space Interaction of tethered groups in diphospha peri-substituted naphthalenes",

abstract = "NMR properties of 1,8-diphosphanaphthalenes with prerequisites for strong through-space interaction were studied. The exceptional magnitude of (4)J(PP) 246 Hz was found in Nap[P(NMe2)(2)][P(OMe)(NMe2)] (Nap = naphthalene-1,8-diyl). The P-III, P-V mixed valence systems Nap[P(E)(OMe)(2)][P(OMe)(2)] (E = O, S, Se) show much lower magnitudes of through-space interaction than expected.",

keywords = "chalcogenides, phosphorus, strained molecules, P-III, 1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE, COORDINATION, DERIVATIVES",

author = "Petr Kilian and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2004",

month = apr,

doi = "10.1080/10426500490427826",

language = "English",

volume = "179",

pages = "999--1002",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor and Francis",

number = "4-5",

}

TY - JOUR

T1 - Through Space Interaction of tethered groups in diphospha peri-substituted naphthalenes

AU - Kilian, Petr

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/4

Y1 - 2004/4

N2 - NMR properties of 1,8-diphosphanaphthalenes with prerequisites for strong through-space interaction were studied. The exceptional magnitude of (4)J(PP) 246 Hz was found in Nap[P(NMe2)(2)][P(OMe)(NMe2)] (Nap = naphthalene-1,8-diyl). The P-III, P-V mixed valence systems Nap[P(E)(OMe)(2)][P(OMe)(2)] (E = O, S, Se) show much lower magnitudes of through-space interaction than expected.

AB - NMR properties of 1,8-diphosphanaphthalenes with prerequisites for strong through-space interaction were studied. The exceptional magnitude of (4)J(PP) 246 Hz was found in Nap[P(NMe2)(2)][P(OMe)(NMe2)] (Nap = naphthalene-1,8-diyl). The P-III, P-V mixed valence systems Nap[P(E)(OMe)(2)][P(OMe)(2)] (E = O, S, Se) show much lower magnitudes of through-space interaction than expected.

KW - chalcogenides

KW - phosphorus

KW - strained molecules

KW - P-III

KW - 1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE

KW - COORDINATION

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=3042519204&partnerID=8YFLogxK

U2 - 10.1080/10426500490427826

DO - 10.1080/10426500490427826

M3 - Article

SN - 1042-6507

VL - 179

SP - 999

EP - 1002

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 4-5

ER -

Through Space Interaction of tethered groups in diphospha peri-substituted naphthalenes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this