Three-layer π-stacking in a dinuclear Cd(NO3)2 complex formed from a new four-armed thiopyridine ligand

David B. Cordes; Lyall R. Hanton

doi:10.1016/j.inoche.2005.07.010

Three-layer π-stacking in a dinuclear Cd(NO₃)₂ complex formed from a new four-armed thiopyridine ligand

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Abstract

The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene (2tet) was synthesized and reacted with
Cd(NO₃)₂ to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II)
centres and displayed an intramolecular three-layered p-stacking arrangement.

Original language	English
Pages (from-to)	967-970
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	8
Early online date	8 Sept 2005
DOIs	https://doi.org/10.1016/j.inoche.2005.07.010
Publication status	Published - Sept 2005

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title = "Three-layer π-stacking in a dinuclear Cd(NO3)2 complex formed from a new four-armed thiopyridine ligand",

abstract = "The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene (2tet) was synthesized and reacted with Cd(NO3)2 to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II) centres and displayed an intramolecular three-layered p-stacking arrangement.",

author = "Cordes, \{David B.\} and Hanton, \{Lyall R.\}",

year = "2005",

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doi = "10.1016/j.inoche.2005.07.010",

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AU - Cordes, David B.

AU - Hanton, Lyall R.

PY - 2005/9

Y1 - 2005/9

N2 - The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene (2tet) was synthesized and reacted with Cd(NO3)2 to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II) centres and displayed an intramolecular three-layered p-stacking arrangement.

AB - The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene (2tet) was synthesized and reacted with Cd(NO3)2 to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II) centres and displayed an intramolecular three-layered p-stacking arrangement.

UR - https://www.scopus.com/pages/publications/26844477207

U2 - 10.1016/j.inoche.2005.07.010

DO - 10.1016/j.inoche.2005.07.010

M3 - Article

SN - 1387-7003

VL - 8

SP - 967

EP - 970

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Three-layer π-stacking in a dinuclear Cd(NO₃)₂ complex formed from a new four-armed thiopyridine ligand

Abstract

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