Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

C  Glidewell; J N  Low; J M S  Skakle; J L  Wardell

doi:10.1107/S0108270105035766

Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

C Glidewell, J N Low, J M S Skakle, J L Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	62
DOIs	https://doi.org/10.1107/S0108270105035766
Publication status	Published - Jan 2006

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title = "Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine",

abstract = "In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.",

author = "C Glidewell and Low, \{J N\} and Skakle, \{J M S\} and Wardell, \{J L\}",

year = "2006",

month = jan,

doi = "10.1107/S0108270105035766",

language = "English",

volume = "62",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2006/1

Y1 - 2006/1

N2 - In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

AB - In both (E,E)-N,N'-bis(4-nitrobenzylidene)butane-1,4-diamine, C18H18N4O4, (111), and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine, C20H22N4O4, (IV), the molecules lie across centres of inversion in space groups P (1) over bar and P2(1)/c, respectively. In (111), the three-dimensional supramolecular structure is built from pi-stacked chains of edge-fused R-2(2)(30) rings, while in (IV), chains of edge-fused R-2(2)(38) rings are linked by dipolar nitro-nitro interactions.

UR - https://www.scopus.com/pages/publications/33645290221

U2 - 10.1107/S0108270105035766

DO - 10.1107/S0108270105035766

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 62

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine

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