Thiophene -2-carbonyl azide

Gene C. Hsu; Laci M. Singer; David B. Cordes; Michael Findlater

doi:10.1107/S1600536813019740

Thiophene -2-carbonyl azide

Gene C. Hsu
, Laci M. Singer
, David B. Cordes
, Michael Findlater

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C₅H₃N₃OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC—H···N^-=N⁺=NR interactions between an aromatic C—H group and an azide moiety which, in conjunction with a
complementary C—H···O=C interaction, forms a nine-membered ring.

Original language	English
Pages (from-to)	o1298
Number of pages	1
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	69
Issue number	8
DOIs	https://doi.org/10.1107/S1600536813019740
Publication status	Published - Aug 2013

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title = "Thiophene -2-carbonyl azide",

abstract = "The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 {\AA}) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC—H···N-=N+=NR interactions between an aromatic C—H group and an azide moiety which, in conjunction with a complementary C—H···O=C interaction, forms a nine-membered ring.",

author = "Hsu, \{Gene C.\} and Singer, \{Laci M.\} and Cordes, \{David B.\} and Michael Findlater",

year = "2013",

month = aug,

doi = "10.1107/S1600536813019740",

language = "English",

volume = "69",

pages = "o1298",

journal = "Acta Crystallographica. Section E, Structure reports online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

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T1 - Thiophene -2-carbonyl azide

AU - Hsu, Gene C.

AU - Singer, Laci M.

AU - Cordes, David B.

AU - Findlater, Michael

PY - 2013/8

Y1 - 2013/8

N2 - The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC—H···N-=N+=NR interactions between an aromatic C—H group and an azide moiety which, in conjunction with a complementary C—H···O=C interaction, forms a nine-membered ring.

AB - The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC—H···N-=N+=NR interactions between an aromatic C—H group and an azide moiety which, in conjunction with a complementary C—H···O=C interaction, forms a nine-membered ring.

U2 - 10.1107/S1600536813019740

DO - 10.1107/S1600536813019740

M3 - Article

SN - 1600-5368

VL - 69

SP - o1298

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

IS - 8

ER -

Thiophene -2-carbonyl azide

Abstract

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