Thionylimido complexes

Liam J. R. McGeachie; Cameron L. Carpenter-Warren; David B. Cordes; Michael Buehl; Steven J. Gray; Guoxiong Hua; Alexandra M. Z. Slawin; J Derek Woollins

doi:10.1002/zaac.202000238

Thionylimido complexes

Liam J. R. McGeachie, Cameron L. Carpenter-Warren, David B. Cordes, Michael Buehl, Steven J. Gray, Guoxiong Hua, Alexandra M. Z. Slawin, J Derek Woollins

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Abstract

An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar₃Sb(NSO)₂), and copper examples (CuBipy(PPh₃)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.

Original language	English
Pages (from-to)	1795-1798
Number of pages	5
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	646
Issue number	22
Early online date	12 Aug 2020
DOIs	https://doi.org/10.1002/zaac.202000238
Publication status	Published - 27 Nov 2020

Keywords

Thionylimide
Thiazate
Complex
Antimony
X-ray structure

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10.1002/zaac.202000238Licence: CC BY

McGeachie-2020-Thionylimido-complexes-ZAAC-CC
Copyright © 2020 The Authors published by Wiley-VCH GmbH · This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Final published version, 397 KBLicence: CC BY

Thionylimido complexes (dataset)
Cordes, D. B. (Creator), Buehl, M. (Creator), Hua, G. (Creator), Slawin, A. M. Z. (Creator) & Woollins, J. D. (Creator), Cambridge Crystallographic Data Centre, 2020
https://dx.doi.org/10.5517/ccdc.csd.cc24mvk6 and 4 more links, https://dx.doi.org/10.5517/ccdc.csd.cc24mvl7, https://dx.doi.org/10.5517/ccdc.csd.cc24mvm8, https://dx.doi.org/10.5517/ccdc.csd.cc24mvn9, https://dx.doi.org/10.5517/ccdc.csd.cc24mvqc (show fewer)
Dataset

Cite this

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title = "Thionylimido complexes",

abstract = "An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.",

keywords = "Thionylimide, Thiazate, Complex, Antimony, X-ray structure",

author = "McGeachie, {Liam J. R.} and Carpenter-Warren, {Cameron L.} and Cordes, {David B.} and Michael Buehl and Gray, {Steven J.} and Guoxiong Hua and Slawin, {Alexandra M. Z.} and Woollins, {J Derek}",

year = "2020",

month = nov,

day = "27",

doi = "10.1002/zaac.202000238",

language = "English",

volume = "646",

pages = "1795--1798",

journal = "Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH, Weinheim",

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TY - JOUR

T1 - Thionylimido complexes

AU - McGeachie, Liam J. R.

AU - Carpenter-Warren, Cameron L.

AU - Cordes, David B.

AU - Buehl, Michael

AU - Gray, Steven J.

AU - Hua, Guoxiong

AU - Slawin, Alexandra M. Z.

AU - Woollins, J Derek

PY - 2020/11/27

Y1 - 2020/11/27

N2 - An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.

AB - An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.

KW - Thionylimide

KW - Thiazate

KW - Complex

KW - Antimony

KW - X-ray structure

U2 - 10.1002/zaac.202000238

DO - 10.1002/zaac.202000238

M3 - Article

SN - 0044-2313

VL - 646

SP - 1795

EP - 1798

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

IS - 22

ER -

Thionylimido complexes

Abstract

Keywords

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Thionylimido complexes (dataset)

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