Thionylimido complexes

Liam J. R. McGeachie, Cameron L. Carpenter-Warren, David B. Cordes, Michael Buehl, Steven J. Gray, Guoxiong Hua, Alexandra M. Z. Slawin, J Derek Woollins

Research output: Contribution to journalArticlepeer-review

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An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.
Original languageEnglish
Pages (from-to)1795-1798
Number of pages5
JournalZeitschrift für Anorganische und Allgemeine Chemie
Issue number22
Early online date12 Aug 2020
Publication statusPublished - 27 Nov 2020


  • Thionylimide
  • Thiazate
  • Complex
  • Antimony
  • X-ray structure


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