Thermal analysis of poly(p-xylylene) and poly(α,α,α',α'-tetrafluoro-p-xylylene)

A O  Oyewale; R Alan Aitken

Thermal analysis of poly(p-xylylene) and poly(α,α,α',α'-tetrafluoro-p-xylylene)

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Abstract

The TG(DTG) and DTA of poly(p-xylylene) and poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylylene) are reported. The degradation was performed from ambient temperature to 900 degrees C in both air and nitrogen. Both polymer degrade faster in air than under nitrogen but the fluorinated polymer eventually decomposed at higher temperature in air than in nitrogen atmosphere. The activation energies of the degradation processes is given.

Original language	English
Pages (from-to)	1393-1401
Number of pages	9
Journal	Journal of Thermal Analysis
Volume	45
Issue number	6
Publication status	Published - Dec 1995

Keywords

activation energy
degradation
differential thermal analysis
poly(alpha,alpha'-difluorostilbene)
poly(p-xylylene)
polystilbene
poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylyene)
p-xylylene
thermogravimetric analysis
vaporization

Cite this

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title = "Thermal analysis of poly(p-xylylene) and poly(α,α,α',α'-tetrafluoro-p-xylylene)",

abstract = "The TG(DTG) and DTA of poly(p-xylylene) and poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylylene) are reported. The degradation was performed from ambient temperature to 900 degrees C in both air and nitrogen. Both polymer degrade faster in air than under nitrogen but the fluorinated polymer eventually decomposed at higher temperature in air than in nitrogen atmosphere. The activation energies of the degradation processes is given.",

keywords = "activation energy, degradation, differential thermal analysis, poly(alpha,alpha'-difluorostilbene), poly(p-xylylene), polystilbene, poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylyene), p-xylylene, thermogravimetric analysis, vaporization",

author = "Oyewale, {A O} and Aitken, {R Alan}",

year = "1995",

month = dec,

language = "English",

volume = "45",

pages = "1393--1401",

journal = "Journal of Thermal Analysis",

issn = "0368-4466",

publisher = "Akademiai Kiado",

number = "6",

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TY - JOUR

T1 - Thermal analysis of poly(p-xylylene) and poly(α,α,α',α'-tetrafluoro-p-xylylene)

AU - Oyewale, A O

AU - Aitken, R Alan

PY - 1995/12

Y1 - 1995/12

N2 - The TG(DTG) and DTA of poly(p-xylylene) and poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylylene) are reported. The degradation was performed from ambient temperature to 900 degrees C in both air and nitrogen. Both polymer degrade faster in air than under nitrogen but the fluorinated polymer eventually decomposed at higher temperature in air than in nitrogen atmosphere. The activation energies of the degradation processes is given.

AB - The TG(DTG) and DTA of poly(p-xylylene) and poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylylene) are reported. The degradation was performed from ambient temperature to 900 degrees C in both air and nitrogen. Both polymer degrade faster in air than under nitrogen but the fluorinated polymer eventually decomposed at higher temperature in air than in nitrogen atmosphere. The activation energies of the degradation processes is given.

KW - activation energy

KW - degradation

KW - differential thermal analysis

KW - poly(alpha,alpha'-difluorostilbene)

KW - poly(p-xylylene)

KW - polystilbene

KW - poly(alpha,alpha,alpha',alpha'-tetrafluoro-p-xylyene)

KW - p-xylylene

KW - thermogravimetric analysis

KW - vaporization

UR - http://www.scopus.com/inward/record.url?scp=33751154232&partnerID=8YFLogxK

M3 - Article

SN - 0368-4466

VL - 45

SP - 1393

EP - 1401

JO - Journal of Thermal Analysis

JF - Journal of Thermal Analysis

IS - 6

ER -

Thermal analysis of poly(p-xylylene) and poly(α,α,α',α'-tetrafluoro-p-xylylene)

Abstract

Keywords

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