The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl

R Alan Aitken; Ryan Inwood; Alexandra Martha Zoya Slawin

doi:10.1007/s10870-020-00876-9

The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl

R Alan Aitken, Ryan Inwood, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

Molecular structures of (R)-2,2'-dimethyl-1,1'-binaphthyl [monoclinic, a = 11.24420 (11), b = 10.56190 (9), c = 13.27180 (13) Å, β = 90.7041 (9)º, space group P2₁] and (±)-2-bromomethyl-2'-dibromomethyl-1,1'-binaphthyl [triclinic, a = 9.4637 (14), b = 9.9721 (18), c = 9.9922 (19) Å, α = 100.093 (5), β = 97.141 (5), γ = 92.585 (4)º, space group P-1] are reported and compared with those of other simple 2,2'-disubstituted-1,1'-binaphthyls.

Original language	English
Pages (from-to)	497-504
Number of pages	8
Journal	Journal of Chemical Crystallography
Volume	51
Issue number	4
Early online date	5 Jan 2021
DOIs	https://doi.org/10.1007/s10870-020-00876-9
Publication status	Published - 28 Oct 2021

Keywords

Binaphthyl
Torsion angle
Inter-ring bond length

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10.1007/s10870-020-00876-9

20JCX binaphthyls rev1
Copyright © The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1007/s10870-020-00876-9
Accepted author manuscript, 2.98 MB

CRITICAT CDT: Critical Resource Catalysis - CRITICAT
Smith, A. D. (PI), Nolan, S. P. (CoI) & Westwood, N. J. (CoI)
EPSRC
1/05/14 → 31/10/22
Project: Standard

The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl (dataset)
Aitken, R. A. (Creator), Inwood, R. (Creator) & Slawin, A. M. Z. (Creator), Cambridge Crystallographic Data Centre, 2021
https://dx.doi.org/10.5517/ccdc.csd.cc25hdgk and one more link, https://dx.doi.org/10.5517/ccdc.csd.cc25hdfj (show fewer)
Dataset

Cite this

@article{d3c695fd519d427eb93435c572d41281,

title = "The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl",

abstract = "Molecular structures of (R)-2,2'-dimethyl-1,1'-binaphthyl [monoclinic, a = 11.24420 (11), b = 10.56190 (9), c = 13.27180 (13) {\AA}, β = 90.7041 (9)º, space group P21] and (±)-2-bromomethyl-2'-dibromomethyl-1,1'-binaphthyl [triclinic, a = 9.4637 (14), b = 9.9721 (18), c = 9.9922 (19) {\AA}, α = 100.093 (5), β = 97.141 (5), γ = 92.585 (4)º, space group P-1] are reported and compared with those of other simple 2,2'-disubstituted-1,1'-binaphthyls.",

keywords = "Binaphthyl, Torsion angle, Inter-ring bond length",

author = "Aitken, {R Alan} and Ryan Inwood and Slawin, {Alexandra Martha Zoya}",

note = "We would like to thank the Engineering and Physical Sciences Research Council and CRITICAT Centre for Doctoral Training for financial support [Grant Code: EP/L016419/1].",

year = "2021",

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doi = "10.1007/s10870-020-00876-9",

language = "English",

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pages = "497--504",

journal = "Journal of Chemical Crystallography",

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T1 - The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl

AU - Aitken, R Alan

AU - Inwood, Ryan

AU - Slawin, Alexandra Martha Zoya

N1 - We would like to thank the Engineering and Physical Sciences Research Council and CRITICAT Centre for Doctoral Training for financial support [Grant Code: EP/L016419/1].

PY - 2021/10/28

Y1 - 2021/10/28

N2 - Molecular structures of (R)-2,2'-dimethyl-1,1'-binaphthyl [monoclinic, a = 11.24420 (11), b = 10.56190 (9), c = 13.27180 (13) Å, β = 90.7041 (9)º, space group P21] and (±)-2-bromomethyl-2'-dibromomethyl-1,1'-binaphthyl [triclinic, a = 9.4637 (14), b = 9.9721 (18), c = 9.9922 (19) Å, α = 100.093 (5), β = 97.141 (5), γ = 92.585 (4)º, space group P-1] are reported and compared with those of other simple 2,2'-disubstituted-1,1'-binaphthyls.

AB - Molecular structures of (R)-2,2'-dimethyl-1,1'-binaphthyl [monoclinic, a = 11.24420 (11), b = 10.56190 (9), c = 13.27180 (13) Å, β = 90.7041 (9)º, space group P21] and (±)-2-bromomethyl-2'-dibromomethyl-1,1'-binaphthyl [triclinic, a = 9.4637 (14), b = 9.9721 (18), c = 9.9922 (19) Å, α = 100.093 (5), β = 97.141 (5), γ = 92.585 (4)º, space group P-1] are reported and compared with those of other simple 2,2'-disubstituted-1,1'-binaphthyls.

KW - Binaphthyl

KW - Torsion angle

KW - Inter-ring bond length

U2 - 10.1007/s10870-020-00876-9

DO - 10.1007/s10870-020-00876-9

M3 - Article

SN - 1074-1542

VL - 51

SP - 497

EP - 504

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 4

ER -

The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl

Abstract

Keywords

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CRITICAT CDT: Critical Resource Catalysis - CRITICAT

Datasets

The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl (dataset)

Cite this