The X-ray Structure of 5-Chlorosalicylaldehyde

R Alan Aitken; Anna L G Gidlow; Russel S Ramsewak; Alexandra Martha Zoya Slawin

doi:10.1007/s10870-012-0382-x

The X-ray Structure of 5-Chlorosalicylaldehyde

R Alan Aitken, Anna L G Gidlow, Russel S Ramsewak, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

5-Chlorosalicylaldehyde [monoclinic, a = 3.800(2), b = 5.595(4), c = 15.174(11) Å, β = 93.221(17)°, space group P21] exhibits an unusual crystal structure with both intramolecular and intermolecular OH to CH=O hydrogen bonding, the latter leading to chains of molecules aligned along the b axis. A survey of previous substituted salicylaldehyde structures shows three main hydrogen bonding patterns: intramolecular only (14), intramolecular and intermolecular dimeric (5), and intramolecular and intermolecular polymeric (3).

Original language	English
Pages (from-to)	65-69
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	43
Issue number	2
Early online date	25 Nov 2012
DOIs	https://doi.org/10.1007/s10870-012-0382-x
Publication status	Published - Feb 2013

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title = "The X-ray Structure of 5-Chlorosalicylaldehyde",

abstract = "5-Chlorosalicylaldehyde [monoclinic, a = 3.800(2), b = 5.595(4), c = 15.174(11) {\AA}, β = 93.221(17)°, space group P21] exhibits an unusual crystal structure with both intramolecular and intermolecular OH to CH=O hydrogen bonding, the latter leading to chains of molecules aligned along the b axis. A survey of previous substituted salicylaldehyde structures shows three main hydrogen bonding patterns: intramolecular only (14), intramolecular and intermolecular dimeric (5), and intramolecular and intermolecular polymeric (3).",

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AU - Gidlow, Anna L G

AU - Ramsewak, Russel S

AU - Slawin, Alexandra Martha Zoya

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Y1 - 2013/2

N2 - 5-Chlorosalicylaldehyde [monoclinic, a = 3.800(2), b = 5.595(4), c = 15.174(11) Å, β = 93.221(17)°, space group P21] exhibits an unusual crystal structure with both intramolecular and intermolecular OH to CH=O hydrogen bonding, the latter leading to chains of molecules aligned along the b axis. A survey of previous substituted salicylaldehyde structures shows three main hydrogen bonding patterns: intramolecular only (14), intramolecular and intermolecular dimeric (5), and intramolecular and intermolecular polymeric (3).

AB - 5-Chlorosalicylaldehyde [monoclinic, a = 3.800(2), b = 5.595(4), c = 15.174(11) Å, β = 93.221(17)°, space group P21] exhibits an unusual crystal structure with both intramolecular and intermolecular OH to CH=O hydrogen bonding, the latter leading to chains of molecules aligned along the b axis. A survey of previous substituted salicylaldehyde structures shows three main hydrogen bonding patterns: intramolecular only (14), intramolecular and intermolecular dimeric (5), and intramolecular and intermolecular polymeric (3).

U2 - 10.1007/s10870-012-0382-x

DO - 10.1007/s10870-012-0382-x

M3 - Article

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EP - 69

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

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ER -

The X-ray Structure of 5-Chlorosalicylaldehyde

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