THE X-RAY CRYSTAL-STRUCTURE OF NA2[PH2PSE2]2.THF.5H2O - A POLYMER CONTAINING 6-MEMBERED SODIUM-WATER RINGS AND SODIUM COORDINATED BY SELENIUM

M J  PILKINGTON; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

doi:10.1016/S0277-5387(00)81339-X

THE X-RAY CRYSTAL-STRUCTURE OF NA2[PH2PSE2]2.THF.5H2O - A POLYMER CONTAINING 6-MEMBERED SODIUM-WATER RINGS AND SODIUM COORDINATED BY SELENIUM

M J PILKINGTON, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

30 Citations (Scopus)

Abstract

Na(x)Se(y), prepared by the reaction of sodium and selenium in liquid ammonia, has been reacted with Ph2PCl in THF/ethanol to give a mixture of Ph2PSeH, Ph2P(Se) OP(Se)Ph2 and the title compound (5) which was characterized by X-ray crystallography. Compound 5 consists of a central polymeric core built up of Na(H2O)6 and Na(H2O)3 (thf)(Se) units with additional hydrogen-bonded Ph2PSe2- anions.

Original language	English
Pages (from-to)	2641-2645
Number of pages	5
Journal	Polyhedron
Volume	10
Issue number	22
DOIs	https://doi.org/10.1016/S0277-5387(00)81339-X
Publication status	Published - 1991

Keywords

METAL-CARBONYLS
ANIONS

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@article{b4c1361d65074fd895f4d0595bc94613,

title = "THE X-RAY CRYSTAL-STRUCTURE OF NA2[PH2PSE2]2.THF.5H2O - A POLYMER CONTAINING 6-MEMBERED SODIUM-WATER RINGS AND SODIUM COORDINATED BY SELENIUM",

abstract = "Na(x)Se(y), prepared by the reaction of sodium and selenium in liquid ammonia, has been reacted with Ph2PCl in THF/ethanol to give a mixture of Ph2PSeH, Ph2P(Se) OP(Se)Ph2 and the title compound (5) which was characterized by X-ray crystallography. Compound 5 consists of a central polymeric core built up of Na(H2O)6 and Na(H2O)3 (thf)(Se) units with additional hydrogen-bonded Ph2PSe2- anions.",

keywords = "METAL-CARBONYLS, ANIONS",

author = "PILKINGTON, {M J} and SLAWIN, {A M Z} and WILLIAMS, {D J} and WOOLLINS, {J D}",

year = "1991",

doi = "10.1016/S0277-5387(00)81339-X",

language = "English",

volume = "10",

pages = "2641--2645",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "22",

}

TY - JOUR

T1 - THE X-RAY CRYSTAL-STRUCTURE OF NA2[PH2PSE2]2.THF.5H2O - A POLYMER CONTAINING 6-MEMBERED SODIUM-WATER RINGS AND SODIUM COORDINATED BY SELENIUM

AU - PILKINGTON, M J

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1991

Y1 - 1991

N2 - Na(x)Se(y), prepared by the reaction of sodium and selenium in liquid ammonia, has been reacted with Ph2PCl in THF/ethanol to give a mixture of Ph2PSeH, Ph2P(Se) OP(Se)Ph2 and the title compound (5) which was characterized by X-ray crystallography. Compound 5 consists of a central polymeric core built up of Na(H2O)6 and Na(H2O)3 (thf)(Se) units with additional hydrogen-bonded Ph2PSe2- anions.

AB - Na(x)Se(y), prepared by the reaction of sodium and selenium in liquid ammonia, has been reacted with Ph2PCl in THF/ethanol to give a mixture of Ph2PSeH, Ph2P(Se) OP(Se)Ph2 and the title compound (5) which was characterized by X-ray crystallography. Compound 5 consists of a central polymeric core built up of Na(H2O)6 and Na(H2O)3 (thf)(Se) units with additional hydrogen-bonded Ph2PSe2- anions.

KW - METAL-CARBONYLS

KW - ANIONS

U2 - 10.1016/S0277-5387(00)81339-X

DO - 10.1016/S0277-5387(00)81339-X

M3 - Comment/debate

SN - 0277-5387

VL - 10

SP - 2641

EP - 2645

JO - Polyhedron

JF - Polyhedron

IS - 22

ER -

THE X-RAY CRYSTAL-STRUCTURE OF NA2[PH2PSE2]2.THF.5H2O - A POLYMER CONTAINING 6-MEMBERED SODIUM-WATER RINGS AND SODIUM COORDINATED BY SELENIUM

Abstract

Keywords

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