The use of ionic liquids in the synthesis of zinc imidazolate frameworks

Gesley A. V. Martins; Peter Joseph Byrne; Phoebe Allan; Simon J. Teat; Alexandra Martha Zoya Slawin; Yang Li; Russell Edward Morris

doi:10.1039/b917348j

The use of ionic liquids in the synthesis of zinc imidazolate frameworks

Gesley A. V. Martins, Peter Joseph Byrne, Phoebe Allan, Simon J. Teat, Alexandra Martha Zoya Slawin, Yang Li, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.

Original language	English
Pages (from-to)	1758-1762
Number of pages	5
Journal	Dalton Transactions
Volume	39
Issue number	7
Early online date	22 Dec 2009
DOIs	https://doi.org/10.1039/b917348j
Publication status	Published - 21 Feb 2010

Keywords

METAL-ORGANIC FRAMEWORKS
DOUBLE 4-RING UNITS
IONOTHERMAL SYNTHESIS
COORDINATION POLYMER
CRYSTAL-STRUCTURE
EXTENDED POLYMORPHISM
MOLECULAR-SIEVES
FLUORIDE IONS
SOLVENT
ALUMINOPHOSPHATE

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10.1039/b917348j

Extending Ionothermal Synthesis: Extending Ionothermal Synthesis
Morris, R. E. (PI) & Lightfoot, P. (CoI)
EPSRC
1/01/08 → 30/06/11
Project: Standard
EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues
Morris, R. E. (PI)
EPSRC
1/07/05 → 31/12/08
Project: Standard

Cite this

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title = "The use of ionic liquids in the synthesis of zinc imidazolate frameworks",

abstract = "Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.",

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author = "Martins, {Gesley A. V.} and Byrne, {Peter Joseph} and Phoebe Allan and Teat, {Simon J.} and Slawin, {Alexandra Martha Zoya} and Yang Li and Morris, {Russell Edward}",

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journal = "Dalton Transactions",

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T1 - The use of ionic liquids in the synthesis of zinc imidazolate frameworks

AU - Martins, Gesley A. V.

AU - Byrne, Peter Joseph

AU - Allan, Phoebe

AU - Teat, Simon J.

AU - Slawin, Alexandra Martha Zoya

AU - Li, Yang

AU - Morris, Russell Edward

PY - 2010/2/21

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N2 - Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.

AB - Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.

KW - METAL-ORGANIC FRAMEWORKS

KW - DOUBLE 4-RING UNITS

KW - IONOTHERMAL SYNTHESIS

KW - COORDINATION POLYMER

KW - CRYSTAL-STRUCTURE

KW - EXTENDED POLYMORPHISM

KW - MOLECULAR-SIEVES

KW - FLUORIDE IONS

KW - SOLVENT

KW - ALUMINOPHOSPHATE

U2 - 10.1039/b917348j

DO - 10.1039/b917348j

M3 - Article

SN - 1477-9226

VL - 39

SP - 1758

EP - 1762

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

The use of ionic liquids in the synthesis of zinc imidazolate frameworks

Abstract

Keywords

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Projects

Extending Ionothermal Synthesis: Extending Ionothermal Synthesis

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues

Cite this