The tin sulfates Sn(SO4)2 and Sn2(SO4)3: crystal structures, optical and thermal properties

Matthias Hämmer; Philip Netzsch; Steffen Klenner; Kai Neuschulz; Mona Struckmann; Mathias S. Wickleder; Michael Daub; Harald Hillebrecht; Rainer Pöttgen; Henning A. Höppe

doi:10.1039/D1DT02189C

The tin sulfates Sn(SO₄)₂and Sn₂(SO₄)₃: crystal structures, optical and thermal properties

Matthias Hämmer, Philip Netzsch, Steffen Klenner, Kai Neuschulz, Mona Struckmann, Mathias S. Wickleder, Michael Daub, Harald Hillebrecht, Rainer Pöttgen, Henning A. Höppe^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report the crystal structures of two tin(iv) sulfate polymorphs Sn(SO₄)₂-I (P2₁/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR₂ = 0.096) and Sn(SO₄)₂-II (P2₁/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR₂ = 0.033). Moreover, the first heterovalent tin sulfate Sn₂(SO₄)₃ is reported which adopts space group P̄ (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, α = 89.007(7)°, β = 86.381(7)°, γ = 73.344(7)°, 1602 independent reflections, 152 refined parameters, wR₂ = 0.059). Finally, SnSO₄ – the only tin sulfate with known crystal structure – was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and ¹¹⁹Sn Mössbauer spectroscopy as well as thermogravimetry and compared.

Original language	English
Pages (from-to)	12913-12922
Number of pages	10
Journal	Dalton Transactions
Issue number	37
Early online date	9 Aug 2021
DOIs	https://doi.org/10.1039/D1DT02189C
Publication status	Published - 7 Oct 2021

Access to Document

10.1039/D1DT02189C

Hämmer_2021_DT_Tin_AAM
Copyright © 2021 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D1DT02189C
Accepted author manuscript, 3.64 MB

CSD 2081697- 2081699: Experimental Crystal Structure Determination
Hämmer, M. (Contributor), Netzsch, P. (Contributor), Klenner, S. (Contributor), Neuschulz, K. (Contributor), Struckmann, M. (Contributor), Wickleder, M. (Contributor), Daub, M. (Contributor), Hillebrecht, H. (Contributor), Pöttgen, R. (Contributor) & Höppe, H. (Contributor), The Cambridge Structural Database, 4 Dec 2021
DOI: 10.25505/fiz.icsd.cc27w5jv, https://dx.doi.org/10.25505/fiz.icsd.cc27w5kw and one more link, https://dx.doi.org/10.25505/fiz.icsd.cc27w5lx (show fewer)
Dataset

Cite this

@article{46c2a74ed6ce44a48c663f440ed15091,

title = "The tin sulfates Sn(SO4)2 and Sn2(SO4)3: crystal structures, optical and thermal properties",

abstract = "We report the crystal structures of two tin(iv) sulfate polymorphs Sn(SO4)2-I (P21/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR2 = 0.096) and Sn(SO4)2-II (P21/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR2 = 0.033). Moreover, the first heterovalent tin sulfate Sn2(SO4)3 is reported which adopts space group {\=P} (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, α = 89.007(7)°, β = 86.381(7)°, γ = 73.344(7)°, 1602 independent reflections, 152 refined parameters, wR2 = 0.059). Finally, SnSO4 – the only tin sulfate with known crystal structure – was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and 119Sn M{\"o}ssbauer spectroscopy as well as thermogravimetry and compared.",

author = "Matthias H{\"a}mmer and Philip Netzsch and Steffen Klenner and Kai Neuschulz and Mona Struckmann and Wickleder, {Mathias S.} and Michael Daub and Harald Hillebrecht and Rainer P{\"o}ttgen and H{\"o}ppe, {Henning A.}",

note = "Funding: H. A. H. and P. N. thank the Deutsche Forschungsgemeinschaft (DFG) for financial support under the project HO 4503/5-1.",

year = "2021",

month = oct,

day = "7",

doi = "10.1039/D1DT02189C",

language = "English",

pages = "12913--12922",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "37",

}

TY - JOUR

T1 - The tin sulfates Sn(SO4)2 and Sn2(SO4)3

T2 - crystal structures, optical and thermal properties

AU - Hämmer, Matthias

AU - Netzsch, Philip

AU - Klenner, Steffen

AU - Neuschulz, Kai

AU - Struckmann, Mona

AU - Wickleder, Mathias S.

AU - Daub, Michael

AU - Hillebrecht, Harald

AU - Pöttgen, Rainer

AU - Höppe, Henning A.

N1 - Funding: H. A. H. and P. N. thank the Deutsche Forschungsgemeinschaft (DFG) for financial support under the project HO 4503/5-1.

PY - 2021/10/7

Y1 - 2021/10/7

N2 - We report the crystal structures of two tin(iv) sulfate polymorphs Sn(SO4)2-I (P21/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR2 = 0.096) and Sn(SO4)2-II (P21/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR2 = 0.033). Moreover, the first heterovalent tin sulfate Sn2(SO4)3 is reported which adopts space group P̄ (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, α = 89.007(7)°, β = 86.381(7)°, γ = 73.344(7)°, 1602 independent reflections, 152 refined parameters, wR2 = 0.059). Finally, SnSO4 – the only tin sulfate with known crystal structure – was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and 119Sn Mössbauer spectroscopy as well as thermogravimetry and compared.

AB - We report the crystal structures of two tin(iv) sulfate polymorphs Sn(SO4)2-I (P21/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR2 = 0.096) and Sn(SO4)2-II (P21/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR2 = 0.033). Moreover, the first heterovalent tin sulfate Sn2(SO4)3 is reported which adopts space group P̄ (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, α = 89.007(7)°, β = 86.381(7)°, γ = 73.344(7)°, 1602 independent reflections, 152 refined parameters, wR2 = 0.059). Finally, SnSO4 – the only tin sulfate with known crystal structure – was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and 119Sn Mössbauer spectroscopy as well as thermogravimetry and compared.

U2 - 10.1039/D1DT02189C

DO - 10.1039/D1DT02189C

M3 - Article

SN - 1477-9226

SP - 12913

EP - 12922

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

The tin sulfates Sn(SO4)2 and Sn2(SO4)3: crystal structures, optical and thermal properties

Abstract

Access to Document

Fingerprint

Datasets

CSD 2081697- 2081699: Experimental Crystal Structure Determination

Cite this

The tin sulfates Sn(SO₄)₂and Sn₂(SO₄)₃: crystal structures, optical and thermal properties