THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

P R  ASHTON; M  GROGNUZ; A M Z  SLAWIN; J F  STODDART; D J  WILLIAMS

THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

P R ASHTON
, M GROGNUZ
, A M Z SLAWIN
, J F STODDART
, D J WILLIAMS

Research output: Contribution to journal › Article › peer-review

Abstract

X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.

Original language	English
Pages (from-to)	6235-6238
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	43
Publication status	Published - 21 Oct 1991

Keywords

COBALT(III) COMPLEXES
ALPHA-CYCLODEXTRIN
BETA-CYCLODEXTRIN
ROTAXANES
RECEPTOR
CYCLOBIS(PARAQUAT-PARA-PHENYLENE)

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title = "THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE",

abstract = "X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.",

keywords = "COBALT(III) COMPLEXES, ALPHA-CYCLODEXTRIN, BETA-CYCLODEXTRIN, ROTAXANES, RECEPTOR, CYCLOBIS(PARAQUAT-PARA-PHENYLENE)",

author = "ASHTON, \{P R\} and M GROGNUZ and SLAWIN, \{A M Z\} and STODDART, \{J F\} and WILLIAMS, \{D J\}",

year = "1991",

month = oct,

day = "21",

language = "English",

volume = "32",

pages = "6235--6238",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "43",

}

TY - JOUR

T1 - THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

AU - ASHTON, P R

AU - GROGNUZ, M

AU - SLAWIN, A M Z

AU - STODDART, J F

AU - WILLIAMS, D J

PY - 1991/10/21

Y1 - 1991/10/21

N2 - X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.

AB - X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.

KW - COBALT(III) COMPLEXES

KW - ALPHA-CYCLODEXTRIN

KW - BETA-CYCLODEXTRIN

KW - ROTAXANES

KW - RECEPTOR

KW - CYCLOBIS(PARAQUAT-PARA-PHENYLENE)

M3 - Article

SN - 0040-4039

VL - 32

SP - 6235

EP - 6238

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 43

ER -

THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

Abstract

Keywords

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