The synthesis of triselenocarbonate complexes of platinum

Stephen Mark Aucott; Colin James Burchell; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1080/10426500490428870

The synthesis of triselenocarbonate complexes of platinum

Stephen Mark Aucott, Colin James Burchell, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60%).

Original language	English
Pages (from-to)	903-906
Number of pages	4
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	179
Issue number	4-5
DOIs	https://doi.org/10.1080/10426500490428870
Publication status	Published - Apr 2004

Keywords

bidentate
carbon diselenide
complexes
metallacycles
triselenoarbonate

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title = "The synthesis of triselenocarbonate complexes of platinum",

abstract = "The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60\%).",

keywords = "bidentate, carbon diselenide, complexes, metallacycles, triselenoarbonate",

author = "Aucott, \{Stephen Mark\} and Burchell, \{Colin James\} and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

year = "2004",

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doi = "10.1080/10426500490428870",

language = "English",

volume = "179",

pages = "903--906",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

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T1 - The synthesis of triselenocarbonate complexes of platinum

AU - Aucott, Stephen Mark

AU - Burchell, Colin James

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/4

Y1 - 2004/4

N2 - The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60%).

AB - The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60%).

KW - bidentate

KW - carbon diselenide

KW - complexes

KW - metallacycles

KW - triselenoarbonate

UR - https://www.scopus.com/pages/publications/3042517373

U2 - 10.1080/10426500490428870

DO - 10.1080/10426500490428870

M3 - Article

SN - 1042-6507

VL - 179

SP - 903

EP - 906

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 4-5

ER -

The synthesis of triselenocarbonate complexes of platinum

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