TY - JOUR
T1 - The synthesis of triselenocarbonate complexes of platinum
AU - Aucott, Stephen Mark
AU - Burchell, Colin James
AU - Slawin, Alexandra Martha Zoya
AU - Woollins, John Derek
PY - 2004/4
Y1 - 2004/4
N2 - The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60%).
AB - The addition of dichloromethane solutions of carbon diselenide to liquid ammonia containing suspensions of platinum bis-phosphine dichlorides [PtCl2 (PRX)(n)] (n = 2, (PRX) = PMe3, PMe2Ph, PMePh2, and M-3, n = 1, (PRX) = dppm, dppe, dppp, dppf) gives, after evaporation of the ammonia and extraction of the reaction residues with dichloromethane, the appropriate platinum bis-phosphine triselenocarbonate complexes in reasonable yields (40-60%).
KW - bidentate
KW - carbon diselenide
KW - complexes
KW - metallacycles
KW - triselenoarbonate
UR - http://www.scopus.com/inward/record.url?scp=3042517373&partnerID=8YFLogxK
U2 - 10.1080/10426500490428870
DO - 10.1080/10426500490428870
M3 - Article
SN - 1042-6507
VL - 179
SP - 903
EP - 906
JO - Phosphorus, Sulfur, and Silicon and the Related Elements
JF - Phosphorus, Sulfur, and Silicon and the Related Elements
IS - 4-5
ER -